hds 废催化剂碱浸取提钒的动力学研究.pdf

24 2 矿　冶　工　程 Vol.24 №2 2004 04 MINING AND METALLURGICAL ENGINEERING April 2004 HDS 1 1 2 刘公召, 安　源, 隋智通 (1., 110023;2. , 110006) 　:-HDS , Na CO -H O、NH HCO -H O NH ·H O 2 3 2 4 3 2 3 2 。 , 3 。 6%, 3%。 、, , 。3 20.50 kJ/mol、45.74 kJ/mol 42.31 kJ/mol。 :HDS ;;; :TF803.21 :A :0253-6099(2004)02-0065-04 Kinetics of Extracting Vanadium fromHDS Spent Catalyst By Alkali Leaching 1 1 2 LIU Gong-hao , AN Yuan , SUI Zhi-tong (1.Shenyang Industrial University of Technology , Shenyang 110023, Liaoning , China ;2.Northeast University , Shenyang 110006, Liaoning , China ) Abstract:Vanadium was extracted from HDS spent catalyst by the air roasting-alkali leaching method.The kinetics of leach- ing vanadium from roasted products was investigated using Na CO -H O, NH HCO -H O and NH ·H O, respectively .Non- 2 3 2 4 3 2 3 2 linear regression of the experimental data was made using least square method, obtaining kinetics equations for vanadium ex- traction by alkali leaching.The absolute error between the equationally-calculated vanadium recovery and the experiementally- measured vanadium recovery was less than 6%, averging below 3%.By comparing the chemical reactions and the resistantes during inner or outer diffusion, the control steps in leaching were confirmed to be chemical reaction.The 3 alkali solutions during leaching had activation energies of 20 .50 kJ/mol, 45.74 kJ/mol and 42.31 kJ/mol, respectively . Key ords:HDS spent catalyst;alkali leaching;vanadium;kinetics 　　HDS 、, , [1～2]