生物柴油干洗纯化方法的研究 study on purification of biodiesel product with dry-cleaning technique.pdfVIP

第 1 卷 第3 期 新 能 源 进 展 Vol. 1 No. 3 2013 年 12 月 ADVANCES IN NEW AND RENEWABLE ENERGY Dec. 2013 文章编号：2095-560X （2013 ）03-0236-04 生物柴油干洗纯化方法的研究* 罗文，李惠文，吕鹏梅，杨玲梅，苗长林，王忠铭，袁振宏† （中国科学院广州能源研究所，中国科学院可再生能源重点实验室，广州510640 ） 摘 要：采用两种不同原料来源的生物柴油进行干洗与水洗纯化实验，对比了干洗、水洗纯化产品及水洗后蒸馏产 品的部分理化性质，包括酸值、闪点、冷滤点、运动粘度及密度，对三种原料来源的生物柴油采用干洗替代水洗工 艺的可行性进行分析。通过对菜籽油、貉子油生物柴油的干洗产品质量的对比，考察lanxess 树脂、罗门哈斯树脂 及吸附剂硅酸镁等对生物柴油的干洗效果，幵研究硅酸镁干洗法的最佳工况。研究结果表明，硅酸镁纯化的菜籽油 及废煎油生物柴油产品测试指标达到国家标准，可以替代水洗法，而离子交换树脂干洗纯化后生物柴油酸值略有偏 高。硅酸镁最适宜干洗温度及时间分别为55℃和30 min 。 关键词：生物柴油；干洗；水洗；硅酸镁；离子交换树脂 中图分类号：TK6 文献标志码：A doi ：10.3969/j.issn.2095-560X.2013.03.006 Study on Purification of Biodiesel Product with Dry-Cleaning Technique LUO Wen, LI Hui-wen, LÜ Peng-mei, YANG Ling-mei, MIAO Chang-lin, WANG Zhong-ming, YUAN Zhen-hong (Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China) Abstract: As to meet the quality requirements of Chinese Standard for biodiesel fuel (GB/T 20828-2007), post transesterification purification is needed. This study compared two purification methods for biodiesel such as dry-cleaning and water-washing. The common method in industry is water-washing, but purification by dry-cleaning with ion exchange resins or magnesium silicate as solid adsorbent shows great potential on energy-saving and process-simplifying. In the study，dry-cleaning was carried out respectively with lanxess resin, Rohm Haas resin and magnesol as adsorbent. These three methods have been used to