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热分析动力学(Thermal analysis kinetics)
热分析动力学(Thermal analysis kinetics)
Thermal analysis kinetics
Basic equation
For common solid phase reactions, the equation of reaction can be expressed as
(1)
The rate of reaction can be expressed in two different forms of equations:
Differential form (2)
and
Integral form (3)
Formula: the fraction of the substance A that has been reacted at alpha t;
T - time;
K - reaction rate constant;
Differential form of F (alpha) - reaction mechanism function;
G (an) - integral form of reaction mechanism function.
Since f (alpha) and G (alpha) are differential forms and integral forms of mechanism function
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