热分析动力学（Thermal analysis kinetics）.doc

热分析动力学（Thermal analysis kinetics） Thermal analysis kinetics Basic equation For common solid phase reactions, the equation of reaction can be expressed as (1) The rate of reaction can be expressed in two different forms of equations: Differential form (2) and Integral form (3) Formula: the fraction of the substance A that has been reacted at alpha t; T - time; K - reaction rate constant; Differential form of F (alpha) - reaction mechanism function; G (an) - integral form of reaction mechanism function. Since f (alpha) and G (alpha) are differential forms and integral forms of mechanism functions respectively, the relation between them is..: (4) The relation between K and reaction temperature T (absolute temperature) can be expressed by the famous Arrhenius equation: (5) Formula: A - apparent anterior factor; E - apparent activation energy; R - universal gas constant. Equations (2) ~ (5) come out under isothermal conditions. When these equations are applied to non isothermal conditions, the following expressions are used: (6) That is: Formula: T0 - DSC curve deviates from baseline starting point temperature (K); Beta heating rate (K = min-1). Thus they can be obtained separately: Two common kinetic equations for heterogeneous systems under isothermal and non isothermal conditions: (isothermal) (7) (non isothermal) (8) The purpose of kinetic studies is to solve the kinetic three factors, E, A and f (alpha), that can describe the above equations in a reaction The DSC curve for the reaction process is shown. In the DSC analysis, the alpha value is equal to Ht/H0, where Ht is the heat of reaction substance A at some point, part of the area under the curve is equivalent to DSC, H0 after the completion of the reaction material A total heat release, equivalent to the total area under DSC curve. Two, differential method 2.1 Achar, Brindley and Sharp methods: The equation is transformed into equations: (9) The two sides are directly logarithmic: (10) It can be seen by formula