人造革合成革中铅、镉、铬、铜、锑含量测定.pdf

人造革合成革中铅、镉、铬、铜、锑含量的测定 赵 洋 ( 中国皮革和制鞋工业研究院，北京 100015) 摘 要：建立了微波消解―ICP-OES准确、快速测定人造革合成革中多种重金属元素的分析方法。 应用具有温度、压力监控功能的高通量微波化学工作站，使样品在硝酸—氢氟酸—过氧化氢混合 酸体系中充分消解，以硼酸消除过量氟离子的影响，采用ICP-OES测定其Pb ，Cd，Cr ，Cu，Sb 元素含量。试验结果表明，优化消解条件和ICP-OES分析条件后，检出限为0.0019～0.0430μg/mL， 3种浓度水平的加标回收率在88.5%～102.8%之间，相对标准偏差小于6.3% 。该方法操作简便、 多种元素可同时测定、检出限低、线性范围宽、干扰小，并具有良好的准确度和精密度，适用于 人造革合成革中重金属元素的日常检测。 关键词：人造革合成革；重金属；微波消解；电感耦合等离子体发射光谱法 Determination of Pd, Cd, Cr, Cu, Sb in Synthetic Leather ZHAO, Yang (China Leather and Footwear Industry Research Institute, Beijing 100015, China) Abstract ：An effective method for the determination of heavy metals in Synthetic Leather by ICP-OES with microwave digestion was developed in this paper. Samples of Synthetic Leather were digested with high throughput microwave chemistry workstation in nitric acid, hydrogen peroxide and fluorhydric acid mixed system, the boric acid is used to eliminate the effect of fluorhydric acid and quantified by ICP-OES. The result shows that the limit of detection was 0.0019～0.043μg/mL, the average recoveries at three levels ranged form 88.5%～102.8%, the relative standard deviations were lower than 6.3% after microwave digestion and ICP-OES analytical condition were optimized. The method has the advantage of simplicity, high sensitivity, wide range of linear and small distraction. The determined results are accurate and the reproducibility is good. It has been applied to routine determination of heavy metals in synthetic leather with satisfactory results. 作者简介：赵洋(1985-)，男，在读硕士，助理工程师，主要从事鞋类、皮革、纺织等商品质量安全检测技 术研究。 1 Key words: synthetic leather; heavy metals; m