聚酯型聚氨酯弹性体的合成和性能研究.pdfVIP

Material Sciences 材料科学, 2016, 6(2), 103-109 Published Online March 2016 in Hans. /journal/ms /10.12677/ms.2016.62013 Synthesis and Performance Research of Polyester Polyurethane Elastomers Feng Yuan, Weicheng Jiao, Yi Hong, Wenbo Liu, Rongguo Wang Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin Heilongjiang nd rd th Received: Mar. 2 , 2016; accepted: Mar. 23 , 2016; published: Mar. 29 , 2016 Copyright © 2016 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract 4,4-Phenyl methane diisocyanate (MDI), poly(1,4-butanediol hexandioic acid) ester (PBA) and 1,4- butanediol (BDO) were used as raw materials, and the pre-polymer method was adopted to syn- thesize MDI-based polyester polyurethane (TPU). The influences of the hard segment content on the relevant performances of TPU were investigated. The results showed that: with the increase of hard segment, the tensile strength of TPU and Tg of soft phase showed a rising trend. But the elon- gation at break and initial thermal decomposition temperature dropped dramatically. Therefore, in order to obtain excellent comprehensive performance, the hard segment content should not be too high. Keywords Polyurethane, Hard Segment Content, Performance 聚酯型聚氨酯弹性体的合成及性能研究 袁 凤，矫维成，洪 毅，刘文博，王荣国 哈尔滨工业大学复合材料与结构研究所，黑龙江 哈尔滨 收稿日期：2016年3月2 日；录用日期：2016年3月23 日；发布日期：2016年3月29 日 文章引用: 袁凤, 矫维成, 洪毅, 刘文博, 王荣国. 聚酯型聚氨酯弹性体的合成及性能研究[J]. 材料科学, 2016, 6(2): 103-109. /10.12677/ms.2016.62013 袁凤 等 摘 要 以4,4-二苯甲烷二异氰酸酯(MDI)、聚己二酸丁二醇酯二醇(PBA)、1,4-丁二醇(BDO)为原料，采用预聚 法合成了MDI基聚酯型聚氨酯弹性体(TPU)。研究了硬段含量对TPU相关性能的影响。研究发