非胺类沥青抗剥落剂的制备及性能.pdfVIP

8 5 Vol. 8, No . 5 2005 10 JOURNAL OF BUILDING M AT ERIALS Oct. , 2005 : 1007- 62 (2005) 05- 0474- 06 1 2 3 2 2 1 朱大章 , 孙晓宇, 吕伟民, 李文哲 , 汪世龙, 倪亚明 ( 1. , 2000 2; 2. , 2000 2; 3. , 2000 2) : 以含磷羟基有机物为主要成分 备了一种非胺类沥青抗剥落剂, 并用水煮法热老 化试验和热重分析研究了其有关性能. 结果表明, 以采用w ( LOP) = 15% , w ( SP) = 5% 配方配 的抗剥落剂掺入沥青后, 可大大提高沥青与酸性石料的粘附性, 使沥青与酸性石 料的粘附性等级由1~ 3 级提高至5 级, 并在热老化后仍能保持良好的效果; 以单十二烷 基磷酸酯和硅胶H 为代表, 通过红外光谱和溶剂淋洗实验初步探讨了抗剥落剂的作用机 理. 结果表明, 单十二烷基磷酸酯在硅胶 H 表面上的吸附符合Langmuir 吸附等温式, 且 这种吸附为化学吸附. : 沥青; 抗剥落剂; 酸性石料; 水煮法; 吸附等温式; 化学吸附 : U 416. 217 : A Preparation and Performance of a Novel Asphalt Antistripping Agent Containing No Amines 1 2 3 ZH U D az hang , S UN X i aoy u , L U We imin 2 2 1 L I Wenz he , WA N G S hil ong , N I Yam ing ( 1. Department of Chemistry, Tongji University, Shanghai 2000 2, China; 2. Analytical Research Centre of Life Science, Tongji University, Shanghai 2000 2, China; 3. Department of Road Airport Engineering, Tongji University , Shanghai 2000 2, China) Abstract: An asphalt antistripping agent w ithout amines w as prepared w ith phosphoric hydroxyl organic compounds as the main component and its performance w as evaluated by w ater boiling method, heatageing and thermalgravimetry. The results show that the optimal formula of the antistripping agent is: w ( LOP) = 15%, w ( SP) = 5% , w hich could improve the adhesion betw een asphalt and acidic stones greatly. It