电解均匀沉淀法制备纳米二氧化锆粉体及其机理.pdfVIP

第26卷 第1期 材 料 科 学 与 工 程 学 报 总第111期 Vo1．26 NO．1 Journal of Materials Science Engineering Feb．2008 文章编号：1673—2812(2008)01—0134—04 电解均匀沉淀法制备纳米二氧化锆粉体及其机理 孙向涛。孙都成 (新疆大学化学化工学院，新疆 乌鲁木齐 830046) 【摘 要】 利用阴离子交换膜将电解槽分为两室．控制阴极电流密度为lOOA／m ，在电解过程中不断消耗阴 极室溶液中H ．促使ZrO 与阴极均匀释放的OH一进行水解反应．形成 ZrO ·xH。O均匀沉淀。在 600*(2焙烧 温度下保温2h，XRD和TEM分析表明：ZrO 粉体为四方晶型，呈球形，粒径约为3O～50nm。讨论了焙烧温度对 纳米 ZrO 粒度的影响。同时对纳米ZrO 形成机理进行了初步的探讨研究。 【关键词】 电解法；二氧化锆；均匀沉淀；纳米粉体 中图分类号：TB383 文献标识码：A Preparation of Nanometer ZrO2 Powders by Electrolytic and Homogeneous Precipitation and its Forming Mechanism ． SUN Xiang-tao，SUN Du-cheng (College of Chemistry and Chemical Engineering．Xin Jiang University，Urumuqi 830046，China) [Abstract] The electrolytic cell was divided ifito the cathode chamber and anode chamber by the anion—exchanging membrane．Under the electrolyzing process with the current density of 1OOA／m。on the cathode hydrogen ions were consumed continually in the cathode chamber．Zirconyl ions were hydrolyzed with hydroxide ions produced homogeneously by electrolyzing on the cathode and homogeneous precipitation of hydrous zirconia were formed．XRD and TEM analyses show that zirconia powders are tetragonal phase and spherical in shape with the average size of particles ranging from 30 to 50 nm cined at 600％ for 2h．The influence of the calcination temperature on nanometer ZrO?particle size is discussed．The after ca1 ． mechanism of forming nanometer ZrO2 powders is elementarily investigated in this paper．