改性介孔碳对全氟辛酸的吸附性能研究.pdfVIP

改性介孔碳对全氟辛酸的吸附性能研究 摘要:全氟辛酸（PFOA）是作为典型全氟化合物中的重要组成在水体中广泛存在着。它因为 所具有的持久、生物蓄积、内分泌干扰和其他潜在毒性等特殊性能而备受社会的关注。全 氟辛酸性质相对较稳定，通过比较传统的化学分解以和生物降解技术处理方法将其去除比 较困难；而与此不同的是，吸附法却能够简介有效迅速地将它们吸附并进而除去它们。研究 对象为分子印迹扩孔介孔碳材料，它是一种通过分子印迹手段，对人工合成的扩孔介孔碳 进行改性和分子印迹技术处理，使其对全氟辛酸具有特定性吸附的能力；并通过对改性介 孔碳进行了红外、扫描电镜、X- 射线衍射（XRD）和吸附等技术检测，对所合成的印记材料进行了一定程度的表征。 对介孔碳分子印迹材料的X- 射线衍射(XRD)分析和红外光谱分析表明，本实 合成的物质具有明显的改性介孔碳的特 征；扫描电镜分析和吸附实 也同样论证了所制备的介孔分子筛具 标准的有序的空间多 孔结构。 关键词：全氟辛酸 改性印迹介孔碳 吸附性能研究 1 Modification of mesoporous carbon on adsorption performance of perfluorinated octane sulfonic acid Abatract: Perfluorinated octylic acid (PFOA) is important in the typical perfluorochemicals widely exists in the water.It is because of the persistent, biological accumulation, endocrine disruption, and other potential toxicity and other special performance and highly social attention.Perfluorinated octylic acid properties are relatively stable, by comparing to traditional chemical decomposition and biodegradation technology processing method to remove more difficult;And the difference is that introduction of adsorption method can effective adsorption and remove them quickly.The object of study for molecularly imprinted enlarge Kong Jiekong carbon material, it is a by means of molecular imprinting, expansion of synthetic Kong Jiekong carbon was modified and the molecular imprinting technology processing, make its have the specificity of the acid adsorption capacity;And through the modification of mesoporous carbon infrared and scanning electron microscopy (sem), X-ray diffraction (XRD) and adsorption techniques such as detection, to a certain extent of synthesis of imprinting materials characterization. Of mesoporous carbon molecularly imprinted materials of X - ray diffraction (XRD) analysis and infrared spectrum analysis shows that this experiment of synthetic material has obvious characteristics of modified mes