络合吸收烟气NO体系中Fe(II)EDTA的制备和表征 柏源，薛建明.DOC

络合吸收烟气NO体系中Fe(II)EDTA的制备和表征 柏源，薛建明，李忠华，王小明 (国电环境保护研究院，江苏省 南京市 210031) Preparation and Characterization of Fe(II)EDTA in the System of Nitric Oxide Removal by Chelate Absorption BAI Yuan, XUE Jian-ming, LI Zhong-hua, WANG Xiao-ming (Guodian Environment Protect Research Institute, Nanjing 210031, Jiangsu Province, China)  ABSTRACT: Fe(II)EDTA was synthesized by complexometry, in which disodium dihydrogen ethylenediaminetetraacetate and ferrous sulfate were used as precursors. The sample was characterized by means of X-ray diffraction(XRD), N2 adsorption desorption isotherm, Fourier transform infrared spectroscopy(FT-IR), X-ray photoelectron spectroscopy(XPS), etc. The as-prepared sample was in amorphous and nanostructure. Fe(II)-EDTA was formed in the preparation, which was comfired by FT-IR and XPS. Furthermore, chemical state of Fe element was mainly found to be Fe2+. With increasing concentration of Fe(II)-EDTA, the efficiengcy of denitrification enhanced, and the optimum concentration was 15 mmol/L. Fe-N bond being created in Fe(II)EDTA was the key factor to removal NO. The effect of the pH value on absorbent slurry was investigated. It was found that the efficiency of denitrification reduced when pH value is decreased. Simultaneously, the existence of SO32- can adjust pH value of absorption and slowed decline in the efficient rate of denitrificaion. KEY WORDS: Fe(II)-EDTA; complexing; coal-fired flue gas; denitrification 摘要：以Na2EDTA和FeSO4为前驱体，采用络合法制备了Fe(II)EDTA。采用X射线衍射(XRD)、氮气吸附－脱附等温线、红外光谱(FT-IR)以及X射线光电子能谱(XPS)等现代表征方法对样品晶体结构、微观结构和化学组成进行了表征。XRD和BET分析结果表明，所制备的配合体晶型为无定形，孔径达到纳米级。FT-IR和XPS证实制备过程中形成了Fe(II)-EDTA，且Fe元素主要以Fe2+形式存在。Fe(II)-EDTA脱硝性能实验结果表明，当Fe(II)-EDTA浓度提高时，脱硝效率随之提高，最佳浓度为15mmol/L。以Fe2+形式形成Fe-N键是Fe(II)-EDTA具备络合NO能力的主要因素。浆液的pH值对脱硝性能起着重要影响，脱硝效率随着pH值的下降而降低。同时还发现SO32-的存在起到缓冲作用，减缓脱硝效率降低幅度。 关键词：Fe(II)-EDTA；络合；燃煤烟气；脱硝  1 引言 根据中国环境监测总站提供的数据，我国2007年的氮氧化物(NOx)排放量为1643.4万吨，其中工业NOx排放量为1261.3万吨，而电力行业占整个工业行业NOx排放量的64.3％，占全国总量的45.5％[1]。根据火电厂未来增容的预测和燃煤增量的预计，“十二五”期间火电厂NOx的排放