球型Pt微粒电极的构建及其对甲醇电氧化的研究.pdfVIP

第19卷第2期 化 学 研 究 Vo1．19 No．2 2008年6月 CHEMICAL RESEARCH Jun．20o8 球型Pt微粒电极的构建及其对甲醇电氧化的研究 李 晶，张玲玲，王 栋，董晓亚，汪振辉 (河南师范大学化学与环境科学学院，河南省环境污染控制重点实验室，河南新乡453007) 摘 要：以镍铬合金为基体，在其表面电化学沉积制备了Pt微粒电极，用扫描电子显微镜(SEM)对电极的表面 形貌进行了表征，电化学方法考察了电极的电化学性能和甲醇在该电极上的电催化行为．结果表明镍铬合金表 面沉积的球型Pt微粒电极对甲醇的电氧化具有良好的催化活性，相同实验条件下，该电极的催化活性比纯Pt电 极高30倍．该电极对甲醇的电氧化显示出较高的催化性能． 关键词：Pt微粒电极；镍铬基体；电催化；甲醇氧化 中图分类号：O 646．54 文献标识码：A 文章编号：1008—1011(2008)02—0069—05 Electrocatalytic Oxidation of Methanol Using Spherical Platinum Microparticles Electrode Deposited on the Nicke1．Chromium Substrate LI Jing，ZHANG Ling—ling，WANG Dong，DONG Xiao—ya，WANG Zhen—hui (College of Chem~try and Environmental Science，Henan Key Laboratoryfor Environmental Pollution Control， Henan Normal University,Xinxiang 453007，Henan，China) Abstract：A novel platinum microparticles electrode loaded on nicke1．chromium alloys substrate was prepared by electro—deposition of platinum salt solution．The physical characterization of the electrode was performed by the scanning electron microscope(SEM)．The electrochemical behavior and the electrocatalytic activity towards methanol oxidation were examined by electrochemical methods．Results from the electrochemical measurements revealed that the platinum microparticles electrode loaded on nicke1．chromium substrate showed a catalytic activity towards methanol oxidation．Under the same con— ditions，the electrocatalytic ability of this electrode was 30 times greater than that of the pure platinum eleetrode．The platinum microparticles electrode loaded on nicke1．chromium substrate showed an im—