双组分聚氨酯胶黏剂的研究.pdfVIP

孙明明等，双组分聚氨酯胶黏剂的研究 V01．32，No．2，2010 双组分聚氨酯胶黏剂的研究 孙明明·，一， 张斌1，一， 张绪刚1,2，李坚辉1， 王磊1 摘要：合成了四种相对分子质量和官能度各不相同的聚酯多元醇，并与MDI反应合成了端羟基及端异氰酸基预聚体，通过 红外光谱对其结构进行了表征。用聚醚多元醇与TDI及HDI反应合成了端异氰酸基预聚体。研究了不同体系的粘接性能及热 部件的修补及材料的结构粘接。 关键词：聚氨酯；室温固化；耐磨；耐蚀 中图分类号：TQ433．432 文献标识码：A 文章编号：1001—0017(2010)02-0023—04 on StudyTwo-componentPolyurethane Adllesives=， and Leil SUN Binl一，ZHANG Jian-huilWANG Ming-min91一，ZHANGXu-gan91”，LI (J．Institute ScienceandChemical ofPetrochemistry，而k如，酒i∞gAcademyofSciences，Harbin150040，Chino；2．CollegeofMaterial Engineering， Harbin EngineeringUnwenity，Harbin150001，China) Abstract：Fourkindsof withdifferentmolecularanddi-ortIi—functionalare polyesterpolyols wei【sht groupssynthesized．Hydroxylgroup— terminatedand 8re with MDIandthetrifunctional a∞ isocyanate-terminatedpolynrethan(PU)prepolymerssynthesizedusing polyesterpoly01．andthey with TDI with examinedFTIR．AseriesofPUadhesivesare also andHDl are preparedusing polyetherpoly01．Thesynthesizedpolyesterpolyols by are results that shear atroom 81e andtheiradhesion determined．Theshow the 35～40MPa，900 prepared pmporties strengths temperature peel are theshear atroom are are6-15kN／mof 5-7kN／mof-OH／-NCO strengths curingsystem，andstrengths temperature20-30MPa，