有机盐对水AOT醇反相微乳体系电导行为的影响.PDF

物理化学学报(Wuli Huaxue Xuebao) 22 Acta Phys. Chim. Sin., 2006, 22(1) ：22耀27 January [Article] /whxb 有机盐对水/AOT/醇反相微乳体系电导行为的影响 晓光 董金凤 高勇 周晓海 洪昕林 ( 汉大学化学与分子科学学院, 武汉 430072) 摘要 用二(2 乙基己基)琥珀酸酯磺酸钠(AOT)为表面活性剂研究了以正构醇(己醇、庚醇、辛醇、癸醇)为连续相 的微乳体系的电导行为, 结果表明只有水/AOT/癸醇体系有水诱导的电导渗滤现象. 研究了有机盐(胆酸钠、水杨 酸钠)及温度对电导行为的影响, 发现庚醇、辛醇体系电导率随胆酸钠浓度的增加而减小, 而癸醇体系电导率不 受影响; 庚醇、癸醇体系的电导率随水杨酸钠浓度的增加而增大; 在5耀40 益范围内ln (电导率的自然对数)与温 度成很好的线性关系, 无论有机盐存在与 都没有温度诱导的渗滤现象. 根据Arrhenius type 公式估算了体系的 电导活化能. 关键词： 醇, 微乳液, 电导率, 渗滤, 有机盐, AOT 中图分类号： O648 The Effect of Organic Salts on the Conductance of the Water/AOT/ Alkanol W/O Microemulsion ZHANG, Xiao Guang DONG, Jin Feng ZHANG, Gao Yong ZHOU, Xiao Hai HONG, Xin Lin (College of Chemistry and Molecular Sciences , Wuhan University, Wuhan 430072, P. R. China) Abstract The conductivity behaviour of water in alkanol (hexanol, heptanol, octanol, decanol) microemulsions, in which AOT was employed as surfactant, was investigated. The percolation phenomenon induced by water was found only in the water/AOT/decanol system. The effects of organic salts (sodium cholate and sodium salicylate) and temperature on conductance were then studied. In heptanol and octanol systems the conductivity was decreased with the increase of sodium cholate concentration, whereas it was increased in the case of sodium salicylate. In decanol system the conductivity was hardly changed in the presence of both organic salts. The values of