介孔钛硅分子筛的表面化学特征及除铅机制研究3 - 环境科学学报.pdf

第 19 卷第 5 期 环 　境 　科 　学 　学 　报 Vol . 19 ,No . 5 1999 年 9 月 AC TA SCIEN T IA E CIRCU M STAN T IA E Sept . ,1999 介孔钛硅分子筛的表面化学特征及除铅机制研 究 ( ) 徐应明　王榕树 　天津大学化工学院化工系 ,天津 　300072 摘要 　以表面活性剂在水溶液中形成的液晶相为模板剂 ,考察了钛含量对制备介孔钛硅分子筛性质的影响;应用表面络合 反应关系式计算了介孔钛硅分子筛表面络合反应的基本特征参数. 研究了溶液p H 值 、温度等对 Pb2 + 离子在介孔钛硅分子 筛表面吸附的影响;并就 Pb2 + 离子在介孔钛硅分子筛表面的吸附动力学、吸附等温线和吸附机理进行了探讨. 关键词 　介孔 ,钛硅分子筛 ,动力学 ,铅净化 ,吸附机理. 2 + Surface characteristics and adsorption mechanism of Pb on meso porous titanosil icate molecular sieve ( ) XU Yingming ,WAN G Rongshu 　Depart ment of Chemical Engineering , Tianjin Universit y , Tianjin 300072 Abstract 　Mesoporous tit anosilicate molecular sieve samples in t he presence of ( CTMA) Br were pre pared ,and t he effect of Si/ Ti molar ratio on t he characteristics of t he samples was investigated . A simpli fied surface complexation model was used to calculate t he conditional binding const ant s for surface com 2 + 2 + plexation of Pb on mesoporous tit anosilicate molecular sieve . Adsorption characteristics of Pb on t he sample were also studied as a function of p H and temperature . Finally ,t he dynamics ,isot herms and mecha 2 + nism of t he adsorption for Pb were discussed . Keywords 　mesopore , TiMCM4 1 ,dynamic ,removal of lead ,adsorption mechanism . 铅的污染和毒害很早就被发现且被广泛的研究[ 1 ,2 ] . 它对人体的主要毒效应是造成贫血 症 ,神经机能失调 ,肝脏和肾组织损伤. 现今 ,美国国家环保局已将饮用水中的铅含量从原先的 005mg/ L 降为 0005mg/ L . 但