不同氧化剂制备的聚苯胺电化学性能研究 Electrochemical performance of polyaniline prepared by different oxidizing agent.pdfVIP
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不同氧化剂制备的聚苯胺电化学性能研究
钟新仙,王芳平,李庆余,胡兴艳,卢胜彬,王红强
(广西师范大学化学化工学院,广西桂林541004)
摘要:以二氧化锰、过硫酸铵作为氧化剂。采用化学原位聚合法在室温下制备得到聚苯胺,并采用扫描电子显微镜
阻抗和恒电流充放电技术测试了以其作为电极的超级电容器的电化学性麓。结果表明。以二氧化锰为氧化剂制备的聚
苯胺(简称为M—PANI)在电流密度为5mA/cm2下的单电极比电容达260
Fig,300次循环后比电容仍有204F/g,比
以过硫酸铵作为氧化剂制备的聚苯胺(简称为N—PANI)具有更好的循环性能和更高的比容量。
关键词:聚苯胺;氧化剂;化学氧化聚合法;超级电容器
中图分类号:TM53 文献标识码:A 文章编号:1002—087
X(2009)09~0781—03
Electrochemicalof different
performancepolyanilinepreparedby
oxidizingagent
ZHONGXin—xian,WANG
Fang—ping,LIQing—yu.HUXing—yan,LuSheng—bin,WANGHong—qiang
r如stitute andChemical Normal
ofChemistry Engineering,GuangxiUniversity,GuilinGuangxi541004,China)
was chemicalin-situ atambient
Abstract:Polyanilinepreparedby polymerizationtemperature,usingmanganese
were
dioxideorammOnium asoxidant.The andstructureof characterized
persulphate morphology polyaniline by
electron transforminfrared
scanningmicroscopy(SEM),Fourierspectroscopy(FTIR)andX—ray
electrochemical ofthe assembledwith were
performancessupercapacitor polyanilineinvestigatedbycyclic
and resultsshowthat
voltammetry,electrochemicalimpedance galvanostaticcharge-discharge.These
spectroscopy
the oftheM——PANIelectrode dioxidewasabout260 atthe
by F/g
specificcapacity preparedmanganese
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