铋对铅酸蓄电池用Pb-Ca-Sn合金性能的影响 The effect of bismuth on the performances of Pb-Ca-Sn alloy for lead-acid batteries.pdfVIP

铋对铅酸蓄电池用Pb—Ca—Sn合金性能的影响 秦春段，王涛，苏勇 (合肥工业大学材料学院，安徽合肥230009) 摘要：实验采用塔菲尔曲线、动电位线性扫描、交流伏安等电化学方法研究了不同铋含量的铅钙 锡铝板栅合金的电化学性能，并用显微硬度计测试硬度。结果表明，添加适量的铋，可以提高合金 的耐腐蚀性，抑制Pb(Ⅱ)的生长，减小阳极膜的阻抗，提高电池的深充／放电性能，提高合金板栅的 显微硬度。但过多的铋反而恶化Pb—Ca合金的电化学性能和机械性能。 关键词：铋；铅钙锡铝舍金；电化学性能；显微硬度 中图分类号：912．9 文献标识码：B 文章编号2011)03-104-05 Theeffectofbismuthonthe ofPb-Ca-Snfor performances alloy lead-acidbatteries Chun-duan，WANGTao，SU QIN Yong MaterialsScienceand (Schoolof Engineering,HefeiUnersityofTechnology, Anhui Hefei 230009,China) Abstract：Theelectrochemicalof withdifferentcontentsofbismuthwere performancesPb—Ca—Sn—Al田ridalloy meansofTafellots．1inear and current investigatedby P sweepingvoltammetryaltematingvohammetry．The microhardnesstesterwas to thehardness．Itwasf．0undthattheintroductionofdefinedamount taken investigate ofbismuth in corrosion the of the resultedincreased resistance。inhibitedPb0，decreased of growth impedance for corrosionfilmofthePb-Ca-Sn-A1whichw鹄favorable its alloy increasingcharge／dischargeproperty．and increasedthemicrohardnessofthe excessivebismuthwoulddeterioratetheelectrochemicaland gridalloy．But of mechanical Pb—Ca performancealloy． Keywords：bismuth；Pb-Ca—-Sn-AIalloy；electrochemical performance；mierohardness 1前言 抗层是降低电池深充／放电性能的主要原因，而电