碳硼烷甲基丙烯酸酯接枝改性真丝研究.PDFVIP

Vol.48 第48卷 No.08, Aug. 2011 2011年08月 第08期 研究与技术 碳硼烷甲基丙烯酸酯接枝改性真丝研究 林锐彬，姜佳美，李战雄 (苏州大学 纺织服装工程学院，苏州 江苏 2502) 摘要：以甲基丙烯酸(碳硼烷甲氧乙基)酯为接枝单体，通过自由基乳液接枝处理真丝，在真丝丝素大分子上引入聚甲基丙烯酸(碳 硼烷甲氧乙基)酯接枝链。以正交试验方案优选接枝改性工艺条件，得到的最优化工艺条件为：单体质量分数为2.6 %、引发剂用 量占单体质量分数5 %、在pH3的情况下反应00 min。以红外光谱和扫描电镜对接枝前后的真丝进行了结构表征，利用热分析研究 了接枝前后真丝的热失重行为。结果表明，接枝处理后真丝耐热性能改善，当接枝率为2. %时，温度达到300 ℃时质量保留率为 92.2 %，高于未处理真丝保留率为89.0 %。 关键词：碳硼烷；真丝；接枝改性；耐热性 中图分类号：TS90.8；O636.9 文献标志码：A 文章编号：00-7003(20)08-005-04 Graft modification on silk with carborane Methacrylate LIN Rin-bin, JIANG Jia-mei, LI Zhan-xiong (College of Textile and Clothing Engineering, Soochow University, Suzhou 215021, China) Abstract: Using 1-Carborano-Methoxyethyl Methacrylate as material, graft modification on silk fiber was studied via emulsion radical graft polymerization. The side chains of poly(1-Carborano-Methoxyethyl Methacrylate) were grafted on the silk fibroin macromolecules. The reaction conditions of graft co- polymerization were optimized by orthogonal scheme and the optimum processing conditions was achieved to be: content of monomer in the emulsion was 2.6 %, initiator was 5 %, and the graft polymerization was kept for 100min at the pH value of 3. The structure of the silk fiber before and after modification was characterized by FI-TR and SEM, and thermal decomposition behavior of silk was identified by thermal analysis technology. The TG result showed that the heat-resistance of grafted silk was improved, when the graft degree up to 21.1 ％, the mass retention of treated silk was 92.2 %