纯净真空铬铁合金化学分析方法（Chemical analysis method of pure vacuum chromium iron alloy）.doc

纯净真空铬铁合金化学分析方法（Chemical analysis method of pure vacuum chromium iron alloy） Determination of chromium by ammonium persulphate oxidation titration 1 scope This standard specifies the method of determination of chromium content by ammonium sulfate titration method, reagent material, instrument and equipment, analysis procedure and calculation of analysis results. This standard is applicable to the determination of chromium content in the pure vacuum micro-carbon ferrochrome alloy, and the measuring range (quality score) : is greater than 40.00%. 2 method feeds Sample with hydrochloric acid, phosphoric acid decomposition, to join the sulfuric acid, chromium with ammonium persulfate oxidation, reduction with sodium chloride, and the price is manganese, N - phenyl anthranilic acid as indicator and ammonium ferrous sulfate standard solution titration. The content of chromium is calculated by the amount of the standard solution. Three reagents 3.1 hydrochloric acid (rho 1.19 g/mL) 3.2 phosphoric acid (rho 1.70 g/mL) 3.3 sulfuric acid (rho 1.84 g/mL) 3.4 silver nitrate solution (10g/L) 3.5 ammonium sulphate solution (200g/L) 3.6 sodium chloride solution (50g/L) 3.7 N -- phenyl anthranilic acid solution (2g/L), prepared using 2g/L solution of anhydrous sodium carbonate solution. 3.8 ammonium sulfate standard solution (0.16 mol/L) 4 samples Sample (drill sample) should be through 0.154 mm sieve hole length not greater than 1.6mm. Take the sieve. 5. Analysis procedure 5.1 try shoes Weigh 0.2000 g test. 5.2 measurement 5.2.1 to sample (5.1) in a 500 ml conical flask, add 10 ml of hydrochloric acid (3.1), 15 ml phosphate (3.2), 10 ml of sulphuric acid (3.3) heating to dissolve, remove a bit cold, thin up to 200 ml, add 10 ml of silver nitrate solution (3.4), 35 ml ammonium persulfate solution (3.5), heating boiling to big bubbles. Add 10mL sodium chloride solution (3.6), boil 3-5min, and remove to cool to room temperature. Q/SJFC. J08-017.1-2008 5.2.2 (5.2.1) water dilute to vol