点板展开剂选择（Point plate expansion agent selection）.docVIP

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2017-08-04 发布于河南
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点板展开剂选择（Point plate expansion agent selection）.doc

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点板展开剂选择（Point plate expansion agent selection） I have just learned the column chromatogram before and I dont know if its useful for you. The choice of expanding agent - online finishing The agent selection has a special book, but I dont. According to my experience, the general compound can use ethyl ester hexane, chloroform methanol, alcohol water, etc., when necessary, acid or alkali. A simple solution is based on your strongest solubility choose a polarity of the solvent (such as alcohol, ethyl cyanide, etc.), according to an actual situation you slowly join weak polarity of solvent (e.g., carbon tetrachloride, petroleum ether and dichloromethane, etc.) the polarity of the regulating system. To get the best possible effect. Tell you my ancestral secret PE (60-90) EtAc/PE = 1:2 EtAc/PE/AcOH = 15:5:1 EtAc AcOH/n - Butanol/H2O = 2:1:1:1 I havent had any problems with these four systems for eight years I have been using ethyl acetate: cyclohexane, continuously adjusting the ratio until a satisfactory Rf value is available, which may be added acid or base, I generally acetic acid and triethylamine. Ive been working on it for years. Try it! Amino acids have special expansion agents, commonly used in butyl alcohol and water, and acid base The choice of an expanded agent is usually mixed solvents: generally, there is a solvent with a large solubility to the sample, and the polarity of the sample is selected and the corresponding system is selected. Ethyl acetate: petroleum ether system Polar large methanol: chloroform system Polar large methanol: water: n-butanol: acetic acid system Drag tail can add a small amount of ammonia or glacial acetic acid. Methanol: chloroform is good for amines I commonly use an expanding agent: chloroform/methanol; Cyclohexane/acetone; Ethyl acetate/petroleum ether; Methanol/pyridine/water; Etc. I have used the expanded system, ben-acetone is used most, by adjusting the different proportions can get better effect My: EtOAc/Hexanes Ch2Cl2 (EtOA