新型钡基高温燃烧固硫剂的研究与应用.PDF

维普资讯 第 53卷 第 11期 化 工 学 报 vO1．53 № 11 2002年 11月 Journalof Ch~nical Industry and Engineering (China) November 2002 新型钡基高温燃烧固硫剂的研究与应用 李 宁 刘维屏 周俊虎。 岑可法。 (浙江大学化学系 、环境科学研究所。、能源洁净利用与环境工程教育部重点实验室 ，浙江 杭州310027) 关键词 钡基吸着剂 钙基吸着剂 高温燃烧 固硫机理 固硫率 中图分类号 TQ 546．5 文献标识码 A 文章编号 0438—1157(2002)11—1198—04 SULFUR CAPTURE MECHANISM AND APPLICATIoN OFNOVEL BARIUM —BASED SoRBENTSATHIGH TEM PERATURE LINing~。LIUWeiping3，ZHOUJllIIhu3andCENKefa3 1DepartmentofChemistry，2InstituteofEnvironmentScience，CleanEnergyandEnvironmentEngineeringKeyLab ofMinistryofEducation，~ jiangUniversity，Hangzhou310027，Zhejiang，China) Abstract Thedesulfurizationtechnologyduringcoalcombustion infurnacehasbeenacompetitivechoicefor middleandsmallindustrialboilerstomeettheenvironmentalprotectionrequirements，withtheadvantageoflow costandconvenientoperation．Theordinarycalcium —basedsorbentssuchaslimestonenadcalcimu carbide residuehave lOW desulfurization efficiency during coal combustion becaues ofCaSO4decomposition．The sulphationproductBaSO4whichdon’tdeocmlmseuntil1580℃ hasmuchbetterthermalstabilitythanCaS04 whichrapidlydeocmposeatabout1300℃ ．A new typeofbarimu —baesdsorbentwith highdesulfurization efficiencywas developed． ZCS intelligentsulfurdetemr ination analyzerwas used to study sulfur acpture mechnaism during thehightemperaturecombustionprocessofcoa1．Inaddition thedynamicsulfuracpture process ofthemixtureofbarimu —baesdsorbentnadaclcimu —basedsorbentwasstudiedindetail． Industrial gratefurnaceexperimentrevealed thatthedesulfurization efficiencyofbarimu ——basedsorbentsoculd reach 35．5％ ．whichishigherthan13．88％ ofc