固定化脂肪酶催化棉籽油及碳酸二甲酯反应制备生物柴油.pdf

2009 38 6 PETROCHEM ICA L TECHNOLOGY # 677# 田 雪, 周 斌, 李 鑫, 陈 芳, 高剑峰 ( , 832003) [] , Novozym 435, N ovozym 435 ( ) , N ovozym 435 , 4 1. 5N ovozym 435 () 12. 5% 50 e 24 h 160 r /m in, 96% ; , N ovozym 435 [] ; ; ; ; ; [] 1000- 8144 ( 2009) 06 - 0677- 05 [ ] TQ 517. 2 [] A Syn thesis of B iod iesel from C ottonseed O il and D im ethy l C arbonate Cataly zed by Imm ob ilized L ipase Ti n Xue, Zhou Bin, LiX in, Chen F ng, G o Ji nfeng (C o llege of L ife Science, Sh iheziUn iversity, Sh ih eziX inji ng 832003, Ch in ) [ A bstract] Synthesis of b iod iesel vi tr nsesterific tion of cottonseed o il w ith d mi ethyl c rbon te c t lyzed by mi m obilized c nd id n t rctic lip se( N ovozym435 ) in t-but no l solvent w s studied. Effects of w ter dd ition m ount, n ( dmi ethyl c rbon te) Bn ( cottonseed oil), re ction temper ture, re ction tmi e, N ovozym 435 dos ge, stir speed ndV ( t-but nol) BV ( dmi ethy l c rbon te) on y ield of f tty cid m ethyl ester w ere investig ted. U nder op tmi l tr nsesterific tion cond itions: n ( d mi ethyl c rbon te) Bn ( cotton seed o il) 4, V ( t-but nol) BV ( dmi ethy l c rbon te) 1. 5, m ss fr ction of Novozym435 12. 5% ( b sed on cotton seed o il), re ction tem per ture 50 e , re ction tmi e 24 h, stir speed 160 r/m in nd w ithout dd ition of w ter, y ield to f tty cid methyl ester w s bove 96% . Reus bility of N ovozym 435 w s mi proved gre tly in comp ring w ith using petro leum ether s so lvent of the re ction sy stem. [ K eyw ord s] biodiesel; cottonseed o i;l d mi et