Mn1.18Cr0.02Fe0.8P0.95-xGexSi0.05化合物的磁热效应 Magnetocaloric Effect in Mn1.18Cr0.02Fe0.8P0.95-xGexSi0.05 Compounds.pdfVIP

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Mn1.18Cr0.02Fe0.8P0.95-xGexSi0.05化合物的磁热效应 Magnetocaloric Effect in Mn1.18Cr0.02Fe0.8P0.95-xGexSi0.05 Compounds.pdf

Mn1.18Cr0.02Fe0.8P0.95-xGexSi0.05化合物的磁热效应 Magnetocaloric Effect in Mn1.18Cr0.02Fe0.8P0.95-xGexSi0.05 Compounds

哈斯朝鲁1,宁君1,何小龙1,伊日勒图1,松林1,特古斯1,黄焦宏2 (1.内蒙古师范大学内蒙古自治区功能材料物理与化学重点实验室,内蒙古呼和浩特010022; 2.包头稀土研究院,内蒙古包头014030) 0.260)系列化合物.通过X射线衍射和磁性测量研究了样品的物相结构和磁热效应。该系列化合物结晶为Fe:P 型六角结构,少量si的添加有利于稳定Fe2P型相.热磁曲线显示该系列化合物没有热滞或具有很小的热滞.该 系列化合物的居里温度随(艳含量的增加而升高,在O—l。5T磁场下,最大等温磁熵变约为8J/k.g·K.结果说明该 系列化合物具有良好的室温磁热效应. 关键词:磁热效应:居里温度;磁熵变;热滞 ’。 一 中图分类号:0482.54 文献标识码:A 文章编号:1001.3830(2010)04.0024-03 Effectin MagnetocaloricMnl.1sCro,02Feo。sPo。95一xGexSi0,05Compounds 0Haschaolul,NING Linl,OTegusl,HUANG Junl,胍Xiao.10ngl,SYiriyoltul,SONG Jiao.hon92 1.Inner and Materials, MongolmKeyLaboratoryforPhysicsChemistryofFunctional Inner Normal 01 0022,China; MongoliaUniversity,Hohhot 2.BaotouResearchInstitute Earths,Baotou014034China ofRare Abstract:Aseries ofMnl wereprepared ball andsolidstatereactionunder and effectin byhigh-energy argonatmosphere.低structuremagnetoealorie milling the were meansof diffractionand compoundsinvestigatedby X-ray magnetic inthe additionofa of of to structure.and smallamountSiiS benefit compoundscrystallizeFe2P.typehexagonal the structure.ThemeasⅧ旧mentsshowedthattheseriesof have lOW stabilizingFe,P—type magnetic compoundsvery thermal forx--0.250.0.255and0.260andevennothermal forx--0.245.TheCurie of hysteresis hy

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