矿物掺合料对水泥基材料孔溶液中氯离子浓聚的影响-硅酸盐学报.PDF

第 43 卷第 4 期 硅 酸 盐 学 报 Vol. 43 ，No. 4 2 0 1 5 年 4 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY April ，2015 DOI ：10.14062/j.issn.0454-5648.2015.04.03 矿物掺合料对水泥基材料孔溶液中氯离子浓聚的影响 胡 翔，史才军，李庆玲，何宗旭，何 稳，吕奎喜 (湖南大学土木工程学院，长沙 410082) 摘 要：研究了不同矿物掺合料掺量对水泥基材料孔溶液中氯离子浓聚系数的影响。结果表明：随着矿物掺合料掺量的增加， 氯离子浓聚系数降低。在 NaCl 溶液中浸泡 91 d 后，除了矿粉取代量为 20% 的试件，其它掺入矿物掺合料硬化浆体试件的氯 离子浓聚系数均低于纯硅酸盐水泥试件。随浸泡液 NaCl 浓度增大，氯离子浓聚系数显著降低。氯离子吸附能力与硬化水泥 浆体内水化产物的特性和数量、Ca(OH)2 含量和孔结构有关。 关键词：水泥基材料；矿物掺合料；氯离子浓聚系数；压滤法 中图分类号：TQ12 文献标志码：A 文章编号：0454–5648(2015)04–0376–10 网络出版时间：2015–04–01 16:15:07 网络出版地址：/kcms/detail/11.2310.TQ1615.025.html Influence of Mineral Admixtures on Chloride Ion Condensation of Pore Solution in Cement-based Materials HU Xiang, SHI Caijun, LI Qingling, HE Zongxu, HE Wen, LÜ Kuixi (College of Civil Engineering, Hunan University, Changsha 410082, China) Abstract: Chloride ion condensation index of hardened cement paste exposed to sodium chloride solutions with different concentrations were determined via pore solution expression. The influence of mineral admixtures content on the chloride ion condensation index in pore solution of concrete was investigated. The results show that the chloride ion condensation decreases with the increase of the mineral admixtures content. The condensation index of specimens with mineral admixtures is lower than that without mineral admixtures, except with 20% slag replacement after 91 d soaking. The increase of chloride concentration in the exposed solution causes a significant redu