Hybrid Materials Filled by NanoSiO Doped （混合材料由NanoSiO掺杂）.pdf

1:1 (2012) Journal of Materials and Applications Crystallization Behavior and Luminescent Properties of Polypropylene Hybrid Materials Filled by Nano-SiO2 Doped Eu3+ Complex 1 1 1 1 1 1 Yanxin Wang , Jianguo Tang , Linjun Huang , Yao Wang , Jixian Liu , Zhen Huang , 1 1 2* Qingsong Xu , Wenfei Shen , Laurence A. Belfiore 1 Institute of Hybrid Materials, Laboratory of New Fiber Materials and Modern Textile-the Growing Base for State Key Laboratory, Qingdao University, Qingdao, Shangdong 266071, China 2 Department of Biological and Chemical Engineering, Colorado State University, Fort Collins, CO 80523, USA E-mail: yanxin_2008@126.com; jianguotangde@. Abstract. A novel modified polypropylene filled by nano-SiO2 doped ternary europium complex with α-thenoyltrifluoroacetone(htta) and 1,10-phenanthroline (phen) [Eu(tta)3phen (EuTP)] was obtained via injection-molded method. Nano-SiO2 doped Eu3+ complex achieved by sol-gel technique. The structural investigations by TEM and XRD indicated that europium complex behaves nanocrystals with diameter of ~20 nm that are embedded onto an amorphous nanoSiO2 (~500 nm) surface. Luminescence and thermogravimetric analysis showed that introducing the europium complex in nanoSiO2 can improve the luminescence properties, thermal stability and increase the compatibility between the pure complex and silica. It was also found that nano-SiO doped Eu3+