熔融共结晶法制备赤藓糖醇-三氯蔗糖共晶体-现代食品科技.PDF

现代食品科技 Modern Food Science and Technology 2017, Vol.33, No.5 熔融共结晶法制备赤藓糖醇-三氯蔗糖共晶体 王海蓉，张春桃，梁文懂 （武汉科技大学化学工程与技术学院，煤炭转化与新型炭材料湖北省重点实验室，湖北武汉 430081） 摘要：共结晶技术是精细化学品、制药等高附加值行业的前沿研究方向。本文以赤藓糖醇为载体，采用熔融共结晶法制备了赤 藓糖醇-三氯蔗糖固态复配产品，应用 TG-DSC、XRD 和 SEM 等对其结构与性能进行了表征分析；结果表明：熔融共结晶法制备的 赤藓糖醇-三氯蔗糖固态复配产品为共晶体，赤藓糖醇-三氯蔗糖共晶体的 DSC 热分解吸热峰的峰顶温度为 156.2 ℃，而三氯蔗糖的热 分解吸热峰的峰顶温度为 134.4 ℃，说明共结晶过程有效提高了共晶体复配产品中三氯蔗糖的热稳定性，共结晶试验中发现晶种加入 量和晶种粒度分布是影响赤藓糖醇-三氯蔗糖共结晶产品粒度分布和堆密度的重要因素；当加入晶种的粒度为 120~200 目，加入量为 10 wt%时，熔融共结晶法制备的赤藓糖醇-三氯蔗糖共晶体产品中 30~60 目的晶体占总质量的91.8%，堆密度可达0.82 g/cm3 。 关键词：共结晶；共晶体；赤藓糖醇；三氯蔗糖 文章篇号：1673-9078(2017)5-228-232 DOI: 10.13982/j.mfst.1673-9078.2017.5.036 Co-crystals and Co-crystallization of Meso-erythritol and Sucralose WANG Hai-rong, ZHANG Chun-tao, LIANG Wen-dong (Wuhan University of Science and Technology of Chemical Engineering and Technology, Hubei Province Key Laboratory of Coal Conversion and New Carbon Materials, Wuhan 430081, China) Abstract: Co-crystallization technologies have been known as the leading edge in the fine chemicals and pharmaceuticals industries. The melt co-crystallization process was adopted to produce the solid recombination product of meso-Erythritol and sucralose, the structure and properties of which had been characterized and analyzed by using TG-DSC, XRD, and SEM. The results indicated that the solid recombination product of meso-Erythritol and sucralose is a co-crystal. The endothermic peak temperatures of the thermal decomposition of the co-crystals and pristine sucralose were found to be 156.2 ℃ and 134.4 ℃, respectively ，indicating co-crystalliza