Sm3+掺杂CaWO4基质的发光.PDF

Advances in Analytical Chemistry 分析化学进展, 2017, 7(2), 139-145 Published Online May 2017 in Hans. /journal/aac /10.12677/aac.2017.72019 Photoluminescence and Energy Transfer Properties of Eu3+-Sm3+ Co-Doped CaWO4 Phosphors Fuzhu Lin Xiamen Products Quality Supervision Inspection Institute, Xiamen Fujian th th th Received: May 9 , 2017; accepted: May 24 , 2017; published: May 27 , 2017 Abstract In this work, a series of Eu3+, Sm3+ singly doped and Eu3+-Sm3+ co-doped CaWO4 phosphors were successfully synthesized via the conventional high temperature state reaction. The XRD results showed that doping Eu3+ and Sm3+ into CaWO4 host did not change the scheelite crystal structure of our samples. The photoluminescence spectra revealed that upon excitation at the excitation wa- velength of host (e.g., 247 nm) could give rise to pumping the Eu3+ and Sm3+ emissions, and, in the meanwhile, using the characteristic excitation wavelength of Sm3+ (e.g., 404 nm) could also induce the Eu3+ emission. In addition, we experimentally found that the optimal Eu3+ doping content which corresponds to the maximum Eu3+ emission intensity was 0.10. Furthermore, the photolu- minescence results found that increasing the Sm3+ doping content in the Eu3+-Sm3+ co-doped Ca- WO4 phosphors could induce an Sm3+ initial emission intensity and then a subsequent decrease but constantly increased the Eu3+ emission intensity. The results we presented here had illustrated that there exists the energy transfer from the CaWO4 host to the Eu3+ and Sm3+ dopants and from the dopant of Sm3+ to the dopant of Eu3+. Keywords