间苯二酚磷酸酯阻燃剂的合成研究.PDFVIP

5 1 ( ) V ol. 5 No. 1 2005 3 JOURNA L O F NAN J ING NORM AL UN IVERS ITY ( ENG INEER ING AND TECHNO LOGY ) M ar. 2005 间苯二酚磷酸酯阻燃剂的合成研究 袁相爱, 杨锦飞, 李 丽 ( , 2 10097) [] , . : 2. 21; 60 , 6 h; 130 , 8 h; A lC l , 3 2% , 90% . , . [] , , [ ] O 634. 5, [] B, [] 2005) 0100 808003 Study on Synthesis of Resorcin Phosphate as F lam e Retardant YUAN X ianga,i YANG J infe,i L I L i ( Schoo l of C hem stry and Env ronm en tal Sc en ce, N anj ng N orm al U n vers ty, J angsu N anj ng 2 10097, Ch na) Abstract: In th s paper w as reported a me thod o fm ak ng resorc n phosphate as flam e retardant from pheno l, resorc n and phosphou s oxych lo r de, w as stud ed the nfluence such factors as m o le rat on, tem pe rature and cata lyst have on the reac t on, and w as estab l shed the best react on cond t on: T he mo lar ra t o o f phosphou s oxychlor de and resorc n s 2. 21. In the f rst step, the react on temperature s 60 , and the reac t on tme s 6 hours. In the second step, the react on tem pe ra ture s 130 , and the react on tm e s 8 hours. A lC l3 s the best cata lyst. Its dosage s 2% o f the tota l am ount o f a ll reactants n the f rst step. T he y e ld reaches 90% . The flam e retardance has been tested n d ffer ent p last c product, w h ch show s tha t resorc n phospha te s a good flam e reta rdant. K ey words: resorc n, synthes s, flam e reta rdant 1 实验部分 , , 1. 1 . 20 90 , :