熔盐法制备八面体Li4Ti5O12电化学性能测试.pdf

A1472 Journal of The Electrochemical Society, 153 8 A1472-A1477 2006 0013-4651/2006/1538/A1472/6/$20.00 © The Electrochemical Society Nanosized Li Ti O Prepared by Molten Salt Method 4 5 12 as an Electrode Material for Hybrid Electrochemical Supercapacitors Liang Cheng, Hai-Jing Liu, Jing-Jun Zhang, Huan-Ming Xiong, and Yong-Yao Xia*,z Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China Nanosized lithium titanium oxide Li Ti O powder has been prepared using LiCl as a high-temperature flux. X-ray diffraction, 4 5 12 scanning electron microscope, and transmission electron microscope measurements indicate that the obtained Li Ti O particles 4 5 12 are uniform and the particle size of Li Ti O powder can be controlled by flux content and heating time. Under the optimal 4 5 12 synthetic condition, the particle-size distribution is narrow 100 nm. The hybrid electrochemical supercapacitors using a nanosized Li Ti O negative electrode in combination with an activated carbon positive electrode show much better rate capa- 4 5 12 bility than those