环氧乙烷在聚乙二醇中溶解度的估算.pdfVIP

环氧乙烷在聚乙二醇中溶解度的估算 1 1 1 2 2 李佳 安维中 张海滨 周立明 朱建民 1 2 ( 中国海洋大学化学化工学院，山东 青岛 266100 ； 辽宁奥克化学股份有限公司，辽宁 辽阳 111003 ) 摘 要：在乙氧基化反应中，环氧乙烷在反应混合物中的溶解度是影响反应动力学和装置操作安全性的重要数据。针对 环氧乙烷的特殊性（难以通过实验来测定汽液平衡数据问题），提出了一种估算环氧乙烷在反应混合物中溶解度的方 法。以乙二醇和三种不同分子量的聚乙二醇为溶剂，测定了120~160℃温度范围内、压力p 0.6MPa 时，环氧乙烷加入 量与系统平衡压力、液相液位的实验数据。建立了基于 UNIFAC 方程的环氧乙烷溶解度计算模型，考查了环氧乙烷在 汽液相中的平衡分配关系。模拟结果同实验数据进行了比较，结果表明了模型的可靠性。建立的模型为乙氧基化动力 学及其数学模型的开发奠定了基础。 关键词：环氧乙烷；溶解度；UNIFAC ；乙氧基化； 中图分类号：TQ 028.8 文献标识码：A Solubility prediction for ethylene oxide in polyethylene glycol 1 1,2 1 2 2 Li Jia , An Weizhong , Zhang Haibin , Zhou Liming , Zhu Jianmin (1Department of Chemical Engineering, Ocean University of China, Qingdao, 266100, Shandong,China; 2.Liaonin Oxiranchem Group, Liaoyang, 111003, Liaonin ,China ) Abstract: Ethylene oxide solubility plays an important role in the ethoxylation because it influences both the reaction kinetics and the behavior and stability of reactors. In this work, because of the characteristic of ethylene oxide that it was difficult to measure the vapor-liquid equilibrium data, the problem of ethylene oxide solubility in reactive mixtures was studied. The solubility runs were carried out under the temperature range 120~160 ℃ and pressure p 0.6 MPa by introducing ethylene glycol and polyethylene glycol with different molar weight as solvents. For each run, weighed amounts of ethylene oxide was added, the equilibrium pressure and liquid level were measured. Based on UNIFAC method, the modeling of ethylene oxide solubility was