玻璃化转变的统一模型理论 2.玻璃化转变中自相似Lennard Jones势函数的不动点.pdfVIP

Unified model theory of the glass transition II ．Fixed point of self-similar Lennard Jones potentials in the glass transition Wu Jialin College of Material Science and Engineering, Donghua University, Shanghai, China (200051) E-mail ：jlwu@ Abstract The existence of fixed point for self-similar Lennard-Jones (L-J) potentials, in local cluster growth phase transition in the glass transition, has been proved using the recursive equation of reinforce- restraint of self-similar potential fluctuation. A series of results have been directly deduced. (a) There are only 8 orders of self-similar hard-spheres in the glass transition. (b) A universal behavior: two orthogonal reduced geometric phase potentials (RGPP), the fast RGPP 3/8 and the slow RGPP 5/8, accompanied with 8 orders of cluster growth phase transitions. (c) The stability condition for fluctuation reinforce-restraint is just the Lindemann ratio that is exactly deduced as 0.1047in this paper. (d) The interface excited energy is an invariable of 1/8ε . The origin and transfer of interface excitation 0 comes of the balance between self-similar L-J potential fluctuation and geometric phase potential fluctuation, which also gives rise to a new attractive potential of –17/16ε , lower than potential well 0 energy –ε , in the self-similar mean field of mean fields of different sizes. (e) The delocalization energy 0 of two-body is exactly the tr