低温烧结新型钛酸钡陶瓷复合材料的介电性能研究 dielectric properties study of novel low-temperature sintering barium titanate ceramics.pdfVIP

32 周 媛等：低温烧结新型钛酸钡陶瓷复合材料的介电性能研究 绝缘材料 2013 ，46(1) 低温烧结新型钛酸钡陶瓷复合材料的 介电性能研究 1 1 2 2 周 媛 ，王田禾 ，靳伏丽 ，胡中石 （1. 国电科学技术研究院，南京 210031 ；2. 保定龙源电气有限公司，河北 保定 071000 ） 摘要：为降低片式多层陶瓷电容器（MLCC ）的成本，研究了适宜低温烧结的陶瓷复合材料配方。向钛酸钡中 添加不同的无机填料，对浆料进行球磨，然后将研磨好的浆料进行压片，低温烧结，制备出适宜低温烧结的陶 瓷复合材料，并对其形貌、强度、介电性能和工艺进行研究。结果表明：添加水玻璃和无机硅胶能使钛酸钡烧 结后形成致密的片材强度大、硬度高、不易碎裂；而添加石墨和蒸馏水则不易形成稳定型片材，强度差；添加水 玻璃可以使复合材料的介电常数显著增加，水玻璃的最佳添加量为3%。 关键词：钛酸钡；九水偏硅酸钠；无机硅胶；石墨；低温烧结；介电常数 + 中图分类号：TM201.4 4 ；TM215 文献标志码：A 文章编号：1009-9239（2013 ）01-0032-04 Dielectric Properties Study of Novel Low-temperature Sintering Barium Titanate Ceramics 1 1 2 2 Zhou Yuan , Wang Tianhe , Jin Fuli , Hu Zhongshi (1. Guodian Science and Technology Research Institute, Nanjing 210031, China; 2. Baoding Longyuan Electrical Co., Ltd., Baoding 071000, China) Abstract: To reduce the cost of multilayer ceramic capacitors(MLCC), a series of experiment formula of barium titanate ceramic composites suitable for low-temperature sintering were studied. The barium tita- nate ceramic composites suitable for low-temperature sintering were prepared by adding various inorganic fillers to the barium titanate and milling the slurry, then pelleting the milled slurry and sintering at low-temperature. The morphology, strength, dielectric properties and processibility were then studied. The results show that the barium titanate adding water glass and inorgan