不同类型水平潜流人工湿地对污水中有机物的降解特性-仪器信息网.DOC

上海崇明岛农田土壤中多氯联苯的残留特征 周婕成1毕春娟1陈振楼1*史贵涛21.华东师范大学地理信息科学教育部重点实验室上海 2000622.中国极地研究中心上海 200136摘要在崇明岛采集了101个耕层土壤样品利用GC-μECD测定了8种多氯联苯(PCBs)对其进行多元统计分析探讨了其可能的污染来源结果表明PCBs浓度范围为ND-261ng/g,均值为56.0ngg.低氯联苯含量和检出率均较高不同土壤利用方式对PCBs残留量有一定影响表现为水稻田土壤大棚蔬菜西瓜田土壤露天蔬菜西瓜田土壤主成分分析和相关性研究低氯联苯同系物间相关性较好污染来源可能为同一类关键词多氯联苯农田土壤崇明中图分类号文献标识码文章编号Residues of polychlorinated biphenyls in agricultural fields of Chongming Island in Shanghai. ZHOU Jie-cheng1, BI Chun-juan1, CHEN Zhen-lou1*, SHI Gui-tao2, XU Shi-yuan1 (1.Key Laboratory of Geo-information Science of the Ministry of Education, School of Resources and Environmental Science, East China Normal University, Shanghai 200062, China；2.Polar Research institute of China, Shanghai 200136, China). China Environmental Science, 2010,30(1):1181~1185 Abstract：Residues concentration of 8 polychlorinated biphenyls (PCBs) congeners in 101 soil samples collected at Chongming Island of Shanghai were determined by GC-μECD. The concentrations of PCBs were between ND and 261ng/g with average of 56.0ng/g. Concentration and detection rate of low chlorinated homologues of PCBs are higher than high chlorinated homologues ones. Residues concentrations of PCBs vary with the changes of agricultural land use. Depended on the residue concentration level, the series of land use appears as following: paddy soil green house vegetable and watermelon soil traditional vegetable and watermelon soil. Principal component analysis (PCA) and correlation analysis were introduced to investigate source of PCBs. The result shows that lower chlorinated homologues of PCBs are well correlated and implies that they maybe originate from similar sources. Key words：polychlorinated biphenyls (PCBs)；agricultural fields；soil；Chongming Island；residue 多氯联苯(PCBs)包含209种同系物,由于其化学性质稳定,电导率低,导热性好,不易燃,20世纪70年代在工业生产中有过广泛的应用.PCBs具有明显的急性毒效应、高残留性、高富集性、环境持久性、远距离扩散性[1-3],成为公众最为关注的全球性污染物[4-5]. 有关PCBs残留的报道主要集中在水体和沉积物,也有工业区典型污染区土壤的有关报道[6-8],然而涉及PCBs同系物在农田土壤中的残留及分布状况的研究还相对较少,现有的关于PCBs污染状况的研究还远不能满足研究与管理的需要.本研究通过对上海崇明岛农田土