新型MCM241固载化铌酸催化氧化环戊烯制备戊二醛.PDFVIP

2004 年第 62 卷 化 学 学 报 Vol. 62 , 2004 第 16 期 , 1467～1471 ACTA CHIMICA SINICA No. 16 , 1467 ～1471 新型 MCM41 固载化铌酸催化氧化环戊烯制备戊二醛 徐建华　　戴维林 　　杨新丽　　曹　勇　　范康年 (复旦大学化学系 　上海市分子催化和功能材料重点实验室 　上海 200433) 通过可溶的草酸配合物将铌酸固载到中孔分子筛 MCM41 上 ,得到含催化氧化活性中心的 Nb O / MCM41 负载型催 摘要 　 2 5 化剂 ,并用 XRD , BET , N 吸附等手段进行了表征. 该催化剂在环戊烯催化氧化制备戊二醛的反应中表现出优良的催化性 2 能 ,环戊烯的转化率高达 100 % ,戊二醛收率达到 50 % ,展现了良好的应用前景. 关键词 　铌酸 ,MCM41 ,环戊烯 ,戊二醛 ,选择氧化 ,过氧化氢 Novel MCM41 Supported Niobium Acid for the Catalytic Oxidation of Cyclopentene to Glutaraldehyde XU , JianHua 　　DAI , WeiLin 　　YANG, XinLi 　　CAO , Yong 　　FAN , KangNian ( Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials , Fudan University , Shanghai 200433) Abstract 　Niobium acid has been doped in MCM41 for the synthesis of novel efficient Nb O / MCM41 catalyst by 2 5 using aqueous Nboxalic acid compounds as the precursor. The catalyst has been characterized by means of XRD , BET , N adsorption and desorption methods and shows a satisfying catalytic performance in the selective oxidation of 2 cyclopentene to glutaraldehyde. The conversion reaches 100 % and the yield has come up to 50 % , suggesting its favora