粉煤灰处理阴离子表面活性剂废水及机理研究 adsorption and its mechanism of anionic surfactant in wastewater by fly ash.pdfVIP

2011年4月 电 力 科 技 与 环 保 第27卷第2期 粉煤灰处理阴离子表面活性剂废水及机理研究 ofanionicsurfactant ash anditsmechanism inwastewater Adsorption byfly 周建飞，周年光 (湖南省电力公司试验研究院环境保护研究所，湖南长沙410007) 摘要：采用粉堞灰作为吸附混凝剂．研究了粉煤灰对废水中阴离子表面活性荆十二烷基磺酸钠(SDS)的去除及机 理。分析了粉煤灰投加量、吸附时间、pH值对废水中SDS去除率的影响，探讨了最佳条件下废水中SDS去除率，研 究了粉煤灰动力学特征。结果表明，在200mL浓度50nlg／L的SDS溶液中，调节pH值为13，加入70 g粉煤灰，搅 拌20rain后，SDS的去除率为83．3％。粉煤灰对SDS的吸附符合Freundlich吸附等温式。 关键词：吸附；阴离子表面活性荆；粉煤灰：废水处理 ashcanbeusedfortheremovalofanionicsurfactantfrom ofsodiumdode— Abstract：Fly wastewater．Adsorption sulfate(SDS)inwastewaterhasbeen effectof factors of cyl synthetic investigated．Thekey includingdosage the timeand onSDSremovalefficiencieswereevaluated．Theconditionsand flyash．adsorptionpH optimum the removal weredetermined．Themechanismwasalso studied． correspondingefficiency adsorption furtherly The thatthe is and with resultsshow SDSremoval increased theincrease efficiency firstly steadysubsequently Of withthe ash anddecreased increaseof time．andde- fly dosage．increasedfirstly subsquently adsorption creasedandincreased withtheincreaseof value．The SDSremoval can to firstly subsequently pH efficiencyup 83．3％when70 ashaddedin200mLwastewaterSDS(50 the valuewas gfly containingmg／L)whenpH