铁镍硫化物及其在生命起源中的可能作用-矿物岩石地球化学通报.PDF

Bu lletin of M ineralogy , Pet rology and Geoch emis t ry V ol. 25 No . 4, Oct . 2006 黄姗姗, 范晨子, 鲁安怀 , 100871 20 世纪80 年代后期国际上众多学者指出, 过渡金属硫化物能 进无氧反应, 可能在生命起源演化过程中起到重要作 用本文介绍了目前流行的生命起源理论, 分析了实验条件下已取得的有机合成成果及相关生命的重要物质( 如丙酮酸乙 酸和一些短的多肽等) 在铁镍硫化物作用下的合成; 讨论了几种可能的有机化合反应机理, 开展铁镍硫化物催化剂性能厌氧 有机合成机理合成条件最优化的研究, 以及古洋底环境, 提供了与地球早期生命起源相关的信息 铁镍硫化物; 催化反应机理; 非生物路径有机物合成; 生命起源 P 57 A 1007- 2 802( 2006) 04- 03 88- 07 IronNickel SulfidesandTheirPossible Roles inthe Originof Life H U A N G Sh an- sh an, FA N Chen- z i, L U A n- huai School of Ear th and Sp ace Sci ences , Peking Univers ity , B eij ing 100 87 1, China Abstract: In th e late 1980s, a hypothesis w as proposed t hat th e t rans it ion m et al su lf ides m ight played a s ignificant role in promot ing ab iotic organic ch em ical react ion , and furt her played imp ort ant role for the origin an d evolut ion of lives. T his pap er has introduced the current ly popular hypoth esis on th e origin of lives an d has briefly analyzed the organic synth et ization achievem ent obtain ed in experim ent. S om e f undam en tal su bstances associat ed w ith lives such as pyru vic acid, acetic acid and som e short pep tides have been successf ully synt hesized under t he cat aly sis of iron nickel s ulfides. Som e pos sible reaction m echanism s of organic synt heses, w h ich are crit ical for th e origins of lives, have been discussed. T he stu dies on t he catalytic propert ies of iron n ick el su lfides, m echan ism s of the abiot ic or- ganosynth esis w it h t rans it ion m