湿热老化过程对桑蚕丝性能与结构的影响.PDFVIP

Vol.49 第49卷 No.10, Oct. 2012 2012年10月 第10期 研究与技术 湿热老化过程对桑蚕丝性能与结构的影响 李欢欢，张聚华，傅吉全 (北京服装学院 材料科学与工程学院，北京 100029) - 摘要：对桑蚕丝织物湿热老化样品进行了相关表征，利用衰减全反射 傅里叶转换光谱技术和红外光谱去卷积拟合计算技术对样品 X 的性能和结构变化情况进行了考察，并用 射线衍射技术考察了样品的结晶度变化规律。结果表明，随着老化时间延长和温湿度的 增加，蚕丝断裂强度及白度总体呈下降趋势；湿热老化下，桑蚕丝的β-sheet结构相对百分含量也随时间延长而下降，且同样湿度 下，温度越高下降越明显；湿热老化下，桑蚕丝β-sheet结构相对百分含量变化、结晶度与断裂强度及白度的变化趋势相关。 关键词：桑蚕丝；湿热老化；傅里叶红外光谱；二级结构 中图分类号：TS101.921 文献标志码：A 文章编号：1001-7003(2012)10-0005-06 Effects of hydrothermal aging process on properties and structure of mulberry silk LI Huan-huan, ZHANG Ju-hua, FU Ji-quan (School of Materials Science Engineering, Beijing Institute of Fashion Technology, Beijing 100029, China) Abstract: This paper describes the relevant surface features of hydrothermal aging samples of mulberry silk fabrics, uses attenuated total reflection - Fourier transform spectrum technique and infrared spectrum deconvolution fitting calculation technique to investigate the change of properties and structure of samples and utilizes X-ray diffraction technique to investigate the varying pattern of degree of crystallinity of samples. The result shows that the breaking strength and whiteness of silk generally present a downtrend with the increase of aging time and humiture; under hydrothermal aging, β-sheet structure relative percentage content of mulberry silk also decreases with the increase of time and the higher the temperature, the greater the decrease under the same humidity; under hydrothermal aging, the β-sheet structure re