合成气甲烷化反应积炭过程的热力学分析 - 计算机工程与科学.pdf

第41卷 第8期 燃摇 料摇 化摇 学摇 学摇 报 Vol.41No.8 2013年8月 Journal of Fuel Chemistry and Technology Aug. 2013 文章编号:0253鄄2409(2013)08鄄0978鄄07 合成气甲烷化反应积炭过程的热力学分析 陈宏刚,王腾达,张摇 锴,牛玉广,杨勇平 (华北电力大学 国家火力发电工程技术研究中心,北京摇 102206) 摘摇 要:建立了煤制替代天然气工艺中合成气甲烷化过程的热力学计算模型,并对该反应体系的10个反应进行了分析计算, 得到了各组分的平衡组成和各反应的标准化学平衡常数。 研究了反应温度、操作压力、原料气组分浓度和产品气循环比等对 催化剂床层积炭的影响,发现容易导致积炭的热力学条件为550~800 益的反应温度和0.1~1.5MPa 的操作压力,且温度在 700 益左右、操作压力低于1.0MPa时催化剂床层积炭量最大。 本研究针对催化剂床层积炭规律提出了低温、相对高压、合理 的原料气组成是有利于缓解催化剂床层积炭、提高产品收率及保持催化剂活性的优化反应操作条件。 关键词:替代天然气;甲烷化;热力学分析;催化剂床层积炭 中图分类号:TQ517.2摇 摇 文献标识码:A Thermodynamic analysis of carbon deposition on catalyst for the production of substitute natural gas CHEN Hong鄄gang,WANG Teng鄄da,ZHANG Kai,NIU Yu鄄guang,YANG Yong鄄ping (North China ElectricPower University,National ThermalPowerEngineering Technology Research Center, Beijing摇 100206,China) Abstract:A comprehensive thermodynamic analysis was made on the carbon deposition behavior for the production of substitute natural gas (SNG) through syngas methanation. The component concentrations and the equilibrium constants of ten reactions involved in the syngas methanation were calculated at different temperatures;the effects of temperature,pressure,and the addition of other compounds in the feed gas on the behavior of carbon deposition were investigated. The results indicated that the catalyst bed is prone to carbon deposition at550~800益 and0.1~1.5MPa;asaresult,lower temperature,higherpressure,anda larger H / 2 COratioare suitableforthemethanationreactions. Theadditionof steaminthefeedgasmayalleviatethecarbon deposition to a large extent,whilst a large amount of CO or CH in feed gasmay lead to carbon depo