氧化铁的制备.doc

四氧化三铁纳米片基金资助：江苏省高技术研究重大基金资助：江苏省高技术研究重大项目（BG2006025）; 江苏省摩擦学重点实验室项目（kjsmcx07004）作者简介：张锡凤(1972－ )，女，江苏省宜兴市人，副教授，博士，E-mail: zhangxf_chzh@163.com张锡凤1) 刘晓光1) 程晓农2) 殷恒波1) 曹智娟1) 郝伟1) 严冲2)1) 江苏大学 化学化工学院，江苏 镇江 2120132) 江苏大学 材料科学与工程学院，江苏 镇江 212013摘要：采用液相化学氧化法，在水体系中，以硫酸亚铁为母体，水合肼为氧化剂，加入吐温-80（Tween-80）为修饰剂，合成了厚约20nm、长约152nm的四氧化三铁纳米片。通过X-射线衍射（XRD）、透射电子显微镜（TEM）、扫描电子显微镜（SEM）和高浓度激光粒度仪对四氧化三铁纳米片进行了表征。将四氧化三铁纳米片加到基础油液体石蜡（LP）中，在UNT-Ⅱ摩擦磨损实验机上考察其作为LP添加剂后的摩擦磨损性能，采用SEM分析了磨损表面形貌和表面膜元素组成及含量。结果表明：与不加四氧化三铁纳米片的LP相比，添加后较大程度的降低了摩擦系数，并获得较小的磨痕直径，显著改善了LP的摩擦性能。四氧化三铁，纳米片，化学还原法，摩擦学Preparation of Fe3O4 Nanopiece and Modification Tribological Property of Liquid Paraffin as Its AdditiveZHANG Xifeng1, LIU Xiaoguang1, CHENG Xiaonong2, YIN Hengbo1, Cao zhijuan1, HAO Wei1, YAN Chong2(1. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013; 2. School of Material Science and Engineering, Jiangsu University, Zhenjiang, 212013. )20nm thick and 152nm length Fe3O4 Nanopieces were synthesized using ferrous sulfate as precursor in water systems, hydrazine hydrate as reductant, polyethylene sorbitan monooleate （Tween-80） as modifier. The as-prepared Fe3O4 Nanopieces were characterized by transmission electron micrographs (TEM), powder X-ray diffraction (XRD), scanning electron microscope (SEM), high concentration laser granularity scatter analyzer. The anti-wear and friction reducing performance of Fe3O4 nanopieces as liquid paraffin additive was investigated on UNT-Ⅱ ball-on-plate friction and wear testers. The worn surface morphology and composition of surface film were analyzed by means of scanning electron microscope (SEM). Compared with pure liquid paraffin, the results indicate that the tribological property of liquid paraffin with Fe3O4 nanopieces is improved, the friction coefficients are decreased, and the worn diameter is lesser.ferroso-ferric oxide; nanowires; synthesis (chemical); tribological propertygranularity scatter纳米金属材料的晶粒尺寸与形貌、表面状态和微结构直接影响到纳米金属的物化性质与用途。目前纳米金属的形貌控制