深圳大气中VOCs的二次有机气溶胶生成潜势.PDF

中国环境科学 2014,34(10) ：2449~2457 China Environmental Science 深圳大气中 VOCs 的二次有机气溶胶生成潜势 王扶潘,朱 乔,冯 凝,刘芮伶,黄晓锋,何凌燕* (北京大学深圳研究生院,环境与能源学院,城市人居环境科学 与技术重点实验室,广东 深圳 518055) 摘要：使用气溶胶生成系数法和产率法,对深圳四季 5 种芳香烃和异戊二烯所生成的二次有机气溶胶(SOA)量分季节计算并比较得出:四季 中除春季外,其余三季产率法计算得到的 SOA 量均高于生成系数法计算的结果, 四季所生成 SOA 的平均值分别为(2.48±2.02)µg/m3 和 (2.10±1.21)µg/m3. 2 种方法计算结果均为夏季 SOA 的生成量最大,秋季和冬季次之,春季最小.生成系数法计算得出人为源和天然源的贡献 分别为 96%和 4%,而产率法得到两种源的贡献分别为 86%和 14%.将生成系数法和产率法计算得到的夏季 SOA 值与实测值进行比较,发现 计算值均低于实测值,分别占实测值的 21%和 31%.最后计算芳香烃和异戊二烯的自由基反应速率得出,与 OH 自由基反应是其生成SOA 最 主要的途径, 比例为 75%,与 NO3 自由基和O3 的反应比例分别为 22%和 3%.在生成 SOA 速度上,苯乙烯的速度最快,苯的速度最慢. 关键词：气溶胶生成系数法；产率法；芳香烃；异戊二烯；二次有机气溶胶 中图分类号：X513 文献标识码：A 文章编号：1000-6923(2014)10-2449-09 The generation potential of secondary organic aerosol of atmospheric VOCs in Shenzhen. WANG Fu-pan, ZHU Qiao, * FENG Ning, LIU Rui-ling, HUANG Xiao-feng, HE Ling-yan (Key Laboratory for Urban Habitat Environmental Science and Technology, School of Environment and Energy, Shenzhen Graduate School, Peking University, Shenzhen 518055, China). China Environmental Science, 2014,34(10)：2449~2457 Abstract ：Both the fractional aerosol coefficients (FAC) and yields (Y) methods was wsed to calculate the secondary organic aerosol (SOA) production from atmospheric volatile aromatics and isoprene in ShenZhen. Throughant the year results from the Yields method were all larger than the results by the FAC method except in spring, and the total average SOA production values were (2.48±2.02) µg/m3 3 and (2.10±1.21) µg/m . The calculated SOA value in the summer was the largest, followed by in the autumn, winter, and spring. By the FAC method, the contribution from anthropogenic sources was 96%, while the contribution from natural sources was