陶瓷复合膜ANovelHydrophilicPolyacrylicacid-复旦大学高分子.PDF

2007 65 Vol. 65, 2007 18 , ACTA CHIMICA SINICA No. 18, · · * ( 200433) (AA) PAA- . FT-IR SEMEDS . , TEOS 5 mL, 175 , 7.5%, ; ; ; ; A Novel Hydrophilic Poly(acrylic acid)-ceramic Composite Membrane ZHANG, Tao-Zhou PING, Zheng-Hua* (Key Laboratory of Molecular Engineering of Polymers, Ministry of Education, Department of Macromolecular Science , Fudan University, Shanghai 200433) Abstract A novel hydrophilic organic-ceramic composite membrane was prepared by low temperature chemical vapor deposition (LTCVD) and free-radical graft polymerization of acrylic acid (AA) onto a po- rous ceramic membrane. By means of FTIR, SEM, EDS and contact angle measurement, the chemical com- position, membrane morphology, elemental distribution and hydrophilicity of the grafting layer were stud- ied. By optimizing the LTCVD and graft polymerization conditions, a selective and permeable membrane for dehydration of alcohol was obtained when LTCVD was performed at 175 with 5 mL of tetraethyl orthosilicate (TEOS) and AA grafting was carried out in solution of 7.5% AA. Keywords low temperature chemical vapor deposition; pervaporation; composite membrane; acrylic acid; graft polymerization (PV) [1], , . . , , , [3] [4] . , , , , [5] [6]