氯化亚砜的酰氯化问题 - 有机交流 - 小木虫论坛 - 学术科研第一（Acyl chlorination of sulfoxide - organic exchange - small wood insects BBS - academic research first）.docVIP

氯化亚砜的酰氯化问题 - 有机交流 - 小木虫论坛 - 学术科研第一（Acyl chlorination of sulfoxide - organic exchange - small wood insects BBS - academic research first） Chlorinated sulfyl chloride - organic exchange - small wooden bug BBS - academic research first. TXT - / / selfishness, let us only see ourselves but no one else. If you send a text to someone you like, he wont go back. Looking at your photos, I think of the impulse to be a black and white wall! Sometimes, not the world is too false, just, we are too naive. [consult] the acyl chloride of sulfone Im doing the chlorination of nitrobenzoic acid, which is solid for nitrobenzoic acid, and the product has a very long reaction time with nitrobenzoyl chloride There are two main problems: 1. Dont know how to choose solvent, if have suitable solvent should be finished in a short time, and if the selection of sulfoxide chloride waste solvent comparison of reaction time to 40 hours, dont know if everyone have good method? 2. Can sulfoxide be recycled when it is chlorinated? With dichloroethane, 60 degrees of reaction, the solid is almost completely dissolved and the reaction is half an hour, usually four hours. Spin off half of the solvent (SOCl2 is basically clean) and then take the next step. Have you done this material? Were also solid dissolving so we can stop the reaction, dont we? This reaction is not reflux with dichlorosulfoxide, DMF catalysis! It doesnt work with him I am sulfoxide chloride with two 80 ° reflux reaction for a day, and then to vacuum distillation of sulfoxide chloride. I didnt recycle dichlorosulfoxide. Dichlorosulfoxide should be steamed very dry, otherwise it will affect the next reaction. So 80 degrees is the reaction one day maybe the solid isnt completely dissolved, right? Im using toluene for the night, and you can use chloroform for 2 hours Synthesis of nitrobenzoyl chloride I want to synthesize it with nitrobenzoic acid and chlorinated sulfoxide, but the reaction is that the sulfoxide has to be clean, so what a