污水深度处理中超滤工艺对有机物的截留模型 - 中国水网.pdf

中国环境科学 2015,35(2) ：420~426 China Environmental Science 污水深度处理中超滤工艺对有机物的截留模型 * 黄韵清,孙 傅, 曾思育 ,董 欣,陈吉宁 (清华大学环境学院,北京 100084) 摘要 ：基于浓差极化现象和膜孔堵塞效应,建立了污水深度处理中超滤工艺对有机物的截留模型.利用中试试验数据率定模型参数并验证 模型的模拟效果.模型验证结果表明,该模型能够较好地模拟超滤工艺出水 UV254 值随时间的变化特征,基于最优参数得到的模拟值与相应 实测值相对误差的绝对值均低于 10%.并且模型参数区域灵敏度分析和不确定性分析结果表明,该模型的结构具有较高的可靠性.应用该模 型研究了过滤时间、通量和进水浓度变化对出水水质的影响.结果表明,在过滤初期膜孔堵塞效应占主导地位并增加超滤膜对有机物的截 -1 -5 留效果,在过滤后期浓差极化现象占主导地位并降低超滤膜对有机物的截留效果;当进水 UV254 浓度恒为 0.1cm 时,通量从 5 ×10 m/s 增至 -4 -5 -1 -1 1×10 m/s,导致 UV254 截留率降低 13%;当通量恒为 5 ×10 m/s 时,进水 UV254 浓度从 0.2cm 降至 0.1cm ,使得出水浓度降低 50%.因此,模 型可应用于模拟进水水质和操作条件对污水深度处理中超滤工艺出水水质的影响,为从预处理、过滤周期和通量等方面改进和优化超滤工 艺提供基础. 关键词：污水深度处理；超滤；截留；有机物；模型 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2015)02-0420-07 Modeling organics rejection during ultrafiltration in advanced wastewater treatment. HUANG Yun-qing, SUN Fu, * ZENG Si-yu , DONG Xin, CHEN Ji-ning (School of Environment, Tsinghua University, Beijing 100084, China). China Environmental Science, 2015,35(2)：420~426 Abstract ：Based on the concentration polarization theory and pore blocking effect, a model was developed to predict organics rejection during ultrafiltration in advanced wastewater treatment. The model was calibrated and validated against data collected from pilot-scale experiments. Results of model validation indicated that the model could well predict the time variations of permeate UV254 during ultrafiltration with absolute relative errors between simulated and observed data less than 10%. Regional sensitivity analysis and uncertainty analysis of model parameters suggested that the