b30Hf35Ni35–xCox 氢分离合金组织及其渗氢性能.pdfVIP

第 21 卷 第 1 期 （自然科学版） Vol. 21 No. 1 2015年2月 JOURNAL OF SHANGHAI UNIVERSITY (NATURAL SCIENCE) Feb. 2015 DOI: 10.3969/j.issn.1007-2861.2014.04.013 Nb30Hf35Ni35–x Cox 氢分离合金组织及其渗氢性能 梁 骁, 郭景杰, 李新 中, 苏彦庆, 傅恒志 (哈尔滨工业大学 材料科学与工程学院, 哈尔滨 150001) 摘摘摘要要要: 通过制备 Nb30Hf35Ni35−x Cox (x = 0, 5, · · · , 35) 合金, 利用 X 射线衍射仪、扫描 电子 显微镜等设备研究合金相组成和铸态组织随 Co 含量 的变化规律. 通过在不 同温度 、压力差条 件下进行渗氢实验, 测定各成分合金 的渗氢性能, 并分析合金成分和渗氢性能之 间的关系. 研 究结果表 明, 随着 Co 含量 的增加, 合金中杂质化合物相的含量逐渐降低, 初生 bcc-Nb 相的体 积分数逐渐减小, 共 晶相 中的 bcc-Nb 相 的体积分数逐渐增大, 合金 的共 晶形态 由棒状共 晶形 态逐渐演变为层片状共 晶形态, 且合金的渗氢性能逐渐提高. 关关关键键键词词词 : Nb-Hf-Ni-Co 合金; 显微组织; 渗氢性能 中中中图图图分分分类类类号号号 : TG 139 文文文献献献标标标志志志码码码 : A 文文文章章章编编编号号号 : 1007-2861(2015)01-0012-08 Microstructure evolution and hydrogen permeation performance of Nb30Hf35Ni35–x COx alloys LIANG Xiao, GUO Jing-jie, LI Xin-zhong, SU Yan-qing, FU Heng-zhi (School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China) Abstract: Nb30Hf35Ni35−x COx (x = 0, 5, · · · , 35) alloys were prepared through tungsten arc-melting. The composition and structure of the alloys was analyzed with scanning elec- tron microscope (SEM) and X-ray diffraction (XRD). Evolution of as-cast structures with the Co content was studied. Hydrogen permeation experiments were conducted at various temperatures and pressure differentials. Relationship between hydrogen permeability and composition of Nb-Hf-Ni (Co) alloys was built. It has been shown that, as the Co content increases, the content of impurities of intermetallic phase in the alloy and volume fraction of the primary bcc-Nb phase gradually reduce, while volume fraction of the bcc-Nb in the eutectic gradually i