熔融灰渣侵蚀耐火材料的界面特性研究 - 物理.pdf

第43卷 第2期 燃摇 料摇 化摇 学摇 学摇 报 Vol.43 No.2 2015年2月 Journal of Fuel Chemistry and Technology Feb. 2015 文章编号:0253鄄2409(2015)02鄄0138鄄07 熔融灰渣侵蚀耐火材料的界面特性研究 徐荣声,林雄超,王永刚 (中国矿业大学(北京) 化学与环境工程学院,北京摇 100083) 摘摇 要:研究了碱酸比不同的3种熔融煤灰(A、J1和J2)在莫来石和刚玉两种耐火材料上的界面特性。 结果表明,A对莫来 石和刚玉都有很好的润湿性,而J1和J2对这两种耐火材料则经历由不完全润湿到润湿的过程。 熔渣与耐火材料(S鄄R)界面 宽度随着接触角减小而增大。 从灰渣开始熔融至1520 益,熔融煤灰J1在耐火材料表面上的接触角随着倾角的增加而减小; 当倾角为20毅时,其接触角突然增大。 SEM鄄EDS分析表明,由于界面反应,A 比J1更容易渗透进入耐火材料内部。 对于碱酸 比不同的煤灰,渗透和酸碱反应是熔渣对耐火材料腐蚀的关键。 关键词:耐火材料;灰渣;侵蚀;界面 中图分类号:TQ545摇 摇 文献标识码:A Morphological and interfacial characterization of molten slags on the refractory surface XU Rong鄄sheng,LIN Xiong鄄chao,WANG Yong鄄gang (School of Chemical and EnvironmentalEngineering, China University of Mining and Technology (Beijing),Beijing摇 100083,China) Abstract:The interfacial properties between three types of coal slags (A,J1 and J2 with various base/ acid ratio)andtworefractorymaterials (mulliteandcorundum)were studied. Theresultsindicatethatthe slagAhas good wettability on both of refractory materials. While, the slags J1/ J2 have experienced the process from incomplete wetting to whole wetting. The contact angles decrease with increasing of interface width of slag and refractory materials (S鄄R). The contact angles of J1 on mullite decrease with increasing of inclination angles from deformation temperatureto 1520益,but significantlyincreasewhentheinclinationangleis20毅. TheSEM鄄 EDSanalysis show thatthequantity of slagApermeatingintotherefractorymaterialismorethanthatofJ1slags because of interfacial reaction. The infusion and acid鄄base reactions are the key factors for the refractory corrosion. Key words:refractory material;slag