典型线路板回收过程排放颗粒物的主要成分和特征.pdf

中国环境科学 2012,32(8) ：1447~1451 China Environmental Science 典型线路板回收过程排放颗粒物的主要成分和特征 1,2 1,2 1,2 1* 1,3 1,3 任照芳 ,黄 渤 ,刘 明 ,毕新慧 ,盛国英 ,傅家谟 (1.中国科学院广州地球化学研究所,有机地球 化学国家重点实验室,广东省环境资源利用与保护重点实验室,广东 广州 510640 ；2. 中国科学院研究生院,北京 100049；3.上海大学环境与化学工程学院,上海 200444) 摘要：分析了南方一典型废旧线路板回收作坊内的空气颗粒物(PM)样品的主要化学组成和特征.结果表明,作坊内的 PM 水平比较高,平均 浓度为(1430±200.8)µg/m3,其组成与其他排放源完全不同.有机物(OM) 占PM 的46.7%~51.6%,主要的有机成分是有机磷酸酯类,包括磷酸三 苯酯(TPP)和其甲基取代化合物、十六酸甲酯、十八酸甲酯、左旋葡聚糖和双酚 A.元素碳(EC)对 PM 的贡献较小.此外,线路板回收过程还 排放了大量重金属,尤其是 Cd, Pb 和 Ni.研究结果表明粗放式的线路板回收工艺给当地环境造成了严重危害. 关键词：线路板；磷酸三苯酯；阻燃剂；电子垃圾；颗粒物；室内空气 中图分类号：X131.1 文献标识码：A 文章编号：1000-6923(2012)08-1447-05 The major components and characteristics of particles emitted during recycling of waste printed circuit boards in a typical e-waste workshop of South China. REN Zhao-fang1,2, HUANG Bo1,2, LIU Ming1,2, BI Xin-hui1*, SHENG Guo-ying1,3, FU Jia-mo1,3 (1.Guangdong Province Key Laboratory of Utilization and Protection of Environmental Resource, State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China；2.Graduate University of Chinese Academy of Sciences, Beijing 100049, China; 3.School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China ). China Environmental Science, 2012,32(8)：1447~1451 Abstract ：Air particle samples from a typical workshop of South China engaged in recycling waste printed circuit boards have been collected and analyzed with respect to chemical constituents. The results show that the composition of particulate matter (PM) from recycling process was totally different from other primary sources. The average concentration of PM was (1430±200.8)µg/m3. Organic matter accounted for