1.3 化学反应热的计算（1.3 calculation of chemical reaction heat）.doc

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1.3 化学反应热的计算（1.3 calculation of chemical reaction heat）.doc

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1.3 化学反应热的计算（1.3 calculation of chemical reaction heat）

1.3 化学反应热的计算（1.3 calculation of chemical reaction heat） 1.3 calculation of heat of chemical reaction A calculation of each lesson first hours practicing law of reaction heat (PEP elective 4) 1. the energy problem is a major issue faced by the human society, H2, CO and CH3OH are important sources of energy, they are 285.8 combustion heat kJ Mol1, 282.5 kJ Mol1, 726.7 kJ Mol1. It is known that CO and H2 can under certain conditions for methanol synthesis CO (g) 2H2 (g) ===CH3OH (L). The thermochemical equation for the synthesis of methanol by CO and H2 is (?) A.CO (g) + 2H2 (g), ===CH3OH (L), H = - 127.4, kJ, mol - 1 B.CO (g) + 2H2 (g), ===CH3OH (L), Delta H = + 127.4, kJ, mol - 1 C.CO (g) + 2H2 (g), ===CH3OH (g), H = - 127.4, kJ, mol - 1 D.CO (g) + 2H2 (g), ===CH3OH (g), Delta H = + 127.4, kJ, mol - 1 Answer A According to the title, the heat of combustion of the three substances can be written out: H2 (g) + O2 (g), ===H2O (L), H1 = - 285.8, kJ, mol - 1 CO (g) O2 (g) ===CO2 (g) is H2 = kJ - 282.5 Mol1. CH3OH (L) O2 (g) ===CO2 (g) 2H2O (L) is H3 = kJ - 726.7 Mol1 3 The law is calculated, namely 1 * 2 + 2 - 3 available: CO (g) + 2H2 (g) ===CH3OH (L) H = H1 + 2 Delta Delta Delta H2 Delta H3 = 2 * (- 285.8 kJ mol - 1) + (282.5 - kJ - mol - 1) (- 726.7 - kJ - mol - 1) = - 127.4 - mol - 1 kJ. 2. gray tin (in powder form) and tin are two allotropes of tin. Known: Sn (s, white) + 2HCl (AQ), ===SnCl2 (AQ) + H2 (g), Delta H1 The Sn (s, grey) 2HCl (AQ) ===SnCl2 (AQ) + H2 (g) H2 The delta H3 = kJ - Mol1 2.1 The following statement is correct () A., Delta H1, Delta H2 B. tin exists in the presence of gray tin at room temperature C. Ash into the tin tin reaction is exothermic reaction D. tin ware, at a temperature below 13.2 degrees Celsius, will destroy itself Answer D Analysis by the know Sn (ash) into Sn (white) is endothermic, when the temperature is below 13.2 degrees centigrade, Sn (white) automatically converted to Sn (ash), so A, B and C are wrong, can only choose D. 3. kn