芳香烃 结构（Aromatic hydrocarbon structure）.docVIP

芳香烃 结构（Aromatic hydrocarbon structure） The tenth chapter, the aromatic aromatic hydrocarbons and aromatic hydrocarbons, characteristics and classification of two isomers and named three, the structure of benzene four, aromatic hydrocarbons and aromatic hydrocarbons from five physical properties six, seven chemical properties of monocyclic aromatic benzene ring, substitution reaction positioning rules eight, polycyclic aromatic hydrocarbons, aromatic ten, nine eleven, named multi functional fullerene I. characteristics and classification of aromatics 1. Characteristics of aromatics Aromatic hydrocarbons are also referred to as aromatic hydrocarbons, also known as aromatic hydrocarbons: A, a highly unsaturated B, not easily by addition reaction and oxidation reaction, easy substitution reaction C, ring the bond lengths of D, ring type pi electron delocalization system by 4n+2 electrons, which accord with the rules of Huckel E and NMR signal ring protons appear in low field 2. Classify a, single ring aromatics B, polycyclic aromatic hydrocarbons C and polycyclic aromatic hydrocarbons Benzene o-xylene 1,2- two benzene ethane naphthalene ethylbenzene tert-butylbenzene styrene (E) -1,2- two styrene 1,3,5- three phenyl benzene Anthracene, phenanthrene, two, aromatics, structural isomerism and nomenclature 1, structural isomerism, lateral chain isomerism and positional isomerism are two cases: n-butylbenzene Side chain isomerism sec- Butylbenzene SBR tert-butylbenzene 1,2,3- trimethyl benzene three toluene Positional isomerism 1,2,4- trimethyl benzene, three toluene 1,3,5- trimethyl benzene is three toluene 2. The nomenclature of aromatic hydrocarbons. A. single ring aromatic hydrocarbons are often based on benzene rings and alkyl groups are substituents: 1- methyl -2- ethyl benzene 1,3- xylene (m xylene) 1- ethyl -4- propyl benzene 2- methyl -4- phenyl pentane B. PAHs can also be substituted as benzene rings when the side chains are more complex: 2,3-, two methyl, -1-, phe