温度对苯并噁嗪共混树脂介电性能的影响 effect of temperature on the dielectric properties of polybenzoxazine blend resin.pdfVIP

22 刘志华等：温度对苯并噁嗪共混树脂介电性能的影响 绝缘材料 2013 ，46(1) 温度对苯并噁嗪共混树脂介电性能的影响 a,b a,b a,b 刘志华 ，袁荞龙 ，黄发荣 （华东理工大学 a. 材料科学与工程学院； b. 特种功能高分子材料及相关技术教育部重点实验室，上海 200237 ） 摘要：合成了对氨基苯炔丙基醚（appe ），与苯酚和多聚甲醛通过Mannich 反应制备了含炔丙基的苯并噁嗪 （P-appe ）。将P-appe 与苯酚/苯胺型苯并噁嗪（PAF ）采用溶液共混的方法制得了共混苯并噁嗪树脂，研究了 PAF 和P-appe 共混树脂的工艺性以及温度对其固化树脂介电性能的影响。结果表明：共混树脂粘度小于50 mPa ·s ，加工窗口为80~200 ℃。共混树脂凝胶过程的活化能为102.1 kJ/mol ，固化树脂的吸水率低于0.44% 。 共混树脂的介电常数随温度升高而上升，介质损耗随频率的增加出现的峰值随温度上升而移向高频。固化 树脂分子内氢键(-OH ···N) 含量随温度的升高而提高。 关键词：苯并噁嗪；共混；工艺性能；介电性能；氢键 + 中图分类号：TM201.4 4 ；TM215 文献标志码：A 文章编号：1009-9239（2013 ）01-0022-05 Effect of Temperature on the Dielectric Properties of Polybenzoxazine Blend Resin Liu Zhihuaa,b, Yuan Qiaolonga,b, Huang Faronga,b (a. School of Materials Science and Engineering; b. Key Laboratory for Specially Functional Polymers and Related Technology, Ministry of Education, East China University of Science and Technology, Shanghai 200237, China) Abstract: A p-aminophenyl propargyl ether(appe) was synthesized, and a propargyl based benzoxazine (P-appe) was prepared with the appe, phenol and paraformaldehyde by Mannich condensation reaction. A benzoxazine blend(PAF/P-appe) was prepared by blending the P-appe and phenol/aniline-based benzoxazine (PAF) in solution, and the processibility of the PAF and P-appe blend resin and the effect of tempera- ture on the dielectric properties of the cured resin were studied. The results sho