基于在线观测的大气PM25中棕色碳吸光贡献估算.PDFVIP

中国环境科学 2017,37(2) ：401~406 China Environmental Science 基于在线观测的大气 PM2.5 中棕色碳吸光贡献估算 * 崔 杰,黄晓锋 ,袁金凤,曹礼明,王 川,兰紫娟,何凌燕 (北京大学深圳研究生院,环境与能源学院,城市人居 环境科学与技术实验室,广东 深圳 518055) 摘要：使用三波长光声黑碳光度计(PASS-3)和气溶胶质谱仪(AMS),于 2011 年秋季在浙江城市点金华和 2014 年夏季河北区域点望都进行 了大气在线观测,采用改进的光吸收 Angstrom 指数(AAE)的方法统计外推黑碳 AAE 值,估算这 2 个典型地区 PM2.5 中棕色碳的吸光贡献. 结果表明:经统计外推获得的金华和望都的黑碳 AAE 在 405nm 下的基准值分别是 1.12 和 0.77,532nm 下的基准值分别是 0.87 和 0.63;进而 估算金华和望都 PM2.5 中的棕色碳在 405nm 下的吸光贡献分别为 9.8%和 22.3%;532nm 下的吸光贡献分别为 5.9%和 15.2%,表明我国大气 中气溶胶棕色碳在短波段下的吸光贡献和辐射强迫影响不可忽视. 关键词：棕色碳(BrC) ；黑碳(BC) ；光吸收系数；光吸收 Angstorm 指数(AAE) 中图分类号：X513 文献标识码：A 文章编号：1000-6923(2017)02-0401-06 Estimation of light absorption by brown carbon in PM2.5 based on on-line measurement. CUI Jie, HUANG * Xiao-feng , YUAN Jin-feng, CAO Li-ming, WANG Chuan, LAN Zi-juan, HE Ling-yan (Key Laboratory for Urban Habitat Environmental Science and Technology, School of Environment and Energy, Peking University Shenzhen Graduate School, Shenzhen 518055, China). China Environmental Science, 2017,37(2)：401~406 Abstract ：Two field campaigns were conducted using a three-wavelength photo-acoustic soot spectrometer (PASS-3) and aerosol mass spectrometers (AMS), including urban site Jinhua during autumn 2011 and rural site Wangdu during summer 2014 in this study. Light absorption of brown carbon with improved Absorption Angstrom Exponent (AAE) method was evaluated by extrapolating the more realistic AAE by “pure” BC (AAE_BC). The AAE_BC were found to be 1.12, 0.77 between 405nm and 781nm, and 0.87, 0.63 between 532nm and 781nm in the campaign of Jinhua and Wangdu, respectively. The contributions of BrC aerosol light absorption of PM2.5 at 405nm were 9.8% and 22.3%, and 5.9% and 15.2% at 532nm in Jinhua and Wangdu, respectively. The result