PET表面含有聚硅氧烷微球的涂层制备和其光散射性能.pdfVIP

Vol. 34 No. 5 ( ) 200810 Journal of East Chin a University of S ien e and Te hnology ( Natural S ien e Edition) 699 : 2008) PET 陆 馨, 辛 忠, 张羽佳 ( 华东理工大学化工学院产品工程系, 化学工程联合国家重点实验室, 上海200237) : 将 径为2~ 9 m 的聚硅氧烷微球作为光散射剂均匀分散于丙烯酸树脂中, 涂布于厚 度为180 m 的聚对苯二甲酸乙二醇酯( PET ) 薄膜表面, 挥发溶剂制得光散射薄膜考察了聚硅 氧烷微球的浓度 径和涂层的厚度对光散射薄膜的透光率和雾度等光学性能的影响结果表明: 聚硅氧烷微球可以在保持较高透光率的情况下, 大幅度地提高光散射薄膜的雾度当 径为5 m 的聚硅氧烷微球的添加质量百分数为25% 涂层厚度为90 m 时, 光散射薄膜的透光率为88%, 雾 度为90%, 有效光散射系数可达79%, 具有最佳的光散射性能 : 聚硅氧烷微球; 光散射薄膜; PET : O634 : A Preparation and Light Scattering Property of Coatings Containing Polysiloxane Microspheres on PETFilm Surface L UX in, X I N Zhong , ZH A N G Yuj ia ( S tate K ey L abor ator y of Chemica Eng ineer ing , D ep ar tment of P r od uct E ng ineer ing , S choo of Che mic a E ng ineering , East China Univ e rs ity of S cie nce and Techno ogy , Shang hai 200237, Ch ina) Abstract: T he poly silox ane mi rospheres varied from 2 m to 9 m as light s attering agents were dis persed in a rylate resin to get a oating solution. T hen the oating solution w as applied to one surfa e of a polyethylene ter ephthalate ( PET ) film having a thi kness of 180 m and dr ied to for m a light s attering film. T he influen e of the on entration and the parti le diameter of the light s attering agents, and the thi kness of the oating on the opti al property of the s attering film w ere studied. T he appli ation of the polysiloxane mi rospheres as light s atter ing agents indi ated that the mi rospher es ould signifi antly impr ove the haze of the s attering film w hile the film still has good transmittan e. When the polysilox ane mi rosphere w ith the diameter of 5 m w as added to the oating w ith the thi kness of 90 m, the m