从手性聚倍半硅氧烷制备螺旋含碳纳米材料.docVIP

从手性聚倍半硅氧烷制备螺旋含碳纳米材料 王庆锋，杨永刚* 苏州大学材料与化学化工学部 ygyang@suda.edu.cn （宋五）手性的、螺旋的碳结构具有高导电性、弹性、光学活性和电磁波吸收性能，在微磁传感器、力学微弹簧、手性传感器和电磁波吸收剂领域有潜在的应用。迄今为止，弹簧状的碳微米、纳米线圈，扭曲的碳纳米带和螺旋碳纳米管已有报道，通常采用化学气相沉积的方法制备这些材料1。但是，这些一维碳纳米结构的手性难以控制。文献报道，聚倍半硅氧烷可以作为前驱体来制备碳材料，且产物能够保留聚倍半硅氧烷的介观结构2，因此，在本工作中，我们首先采用自模板法制备了左手螺旋的聚倍半硅氧烷纳米束，氩气保护下碳化后得到单手螺旋碳/二氧化硅复合物，再利用氢氟酸去除二氧化硅，就得到了左手螺旋的由细微纳米纤维组成的含碳纳米束。拉曼光谱和X-射线衍射图表明，得到的碳结构是无定形的。材料表面出现介孔，来自于超细纳米纤维之间的空隙。反射圆二色谱表征说明，材料具有旋光手性，这种手性部分来自于埃尺度的手性和纳米尺度的螺旋。与此同时，我们采用外模板法制备了单手螺旋的4,4’-亚联苯基聚倍半硅氧烷纳米管， Fig. 1. FESEM and TEM images of the carbonaceous bundles (left); DRCD and DRUV-vis spectra of carbon/silica and carbonaceous bundles (right). 关键词：碳纳米结构，手性，聚倍半硅氧烷，溶胶-凝胶生长 致谢 本研究工作得到了国家自然科学基金（No.和江苏省自然科学基金（No. BK 2011354)的资助。 参考文献 [1] S. Liu , Y. Duan , X. Feng , J. Yang, S. Che, Angew. Chem. Int. Ed. 2013, 52, 6858-62. [2] J. J. E. Moreau , L. Vellutini, M. Wong Chi Man, C. Bied, J. Bantignies, P. Dieudonné, J. Am. Chem. Soc. 2001, 123, 7957-8. [3] C. Zhang , Y. Li , B. Li , Y.Yang, Chem. Asian J. 2013, 8, 2714-21. Single-handed helical carbonaceous nanostructures prepared using chiral polybissilsesquioxanes Qingfeng Wang, Yonggang Yang* Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P.R. China E-mail: ygyang@suda.edu.cn Chiral and helical carbon structures possess high conductivity, elasticity, optical chirality and electromagnetic wave absorption properties, which have potential as micromagnetic sensors, mechanical microsprings, chirality sensors and electromagnetic wave absorbers. Up to now, Spring-like carbon micro/nano-wires, twisted carbon nanoribbons and helical carbon nanotubes have been reported. They are generally prepared by chemical vapor deposition using catalysts, following vapor-liquid-solid and catalytic anisotropy mechanisms. However, the handedness of these one-dimensional carbon nanostructures is difficult to control. In this presentation, Left-handed hel